Development of a semiconductor tree branch-like photoreactor for textile industry effluent treatment.

This paper aimed to develop a new photocatalytic reactor design with a rotary tree branch structure for wastewater treatment in the textile industry. The brass sheet calcined at 500 °C (B500) was used as the photocatalyst and as a substrate for ZnO nanoparticle immobilization (B500ZnO). The photoreactor performance was evaluated toward the photodegradation of an aqueous solution of Reactive Black 5 dye (AS-RB5), raw wastewater (RW), and treated wastewater (TW).

The Effect of Microstructural Changes on Mechanical and Electrochemical Corrosion Properties of Duplex Stainless Steel Aged for Short Periods.

This work reports the effects of microstructural changes due to the secondary phases, in particular sigma (), on the mechanical properties and electrochemical behavior of thermally aged duplex stainless steel (DSS). Structural, morphological, mechanical, and electrochemical characterizations were performed. Sigma phase content increased with increasing aging treatment time.

Cu catalysts supported on CaO/MgO for glycerol conversion to lactic acid in alkaline medium employing a continuous flow reaction system.

The production of lactic acid (LA) from glycerol in alkaline medium was investigated using Cu catalysts supported on CaO, MgO and CaO/MgO ( = 5, 10, 15 wt%), employing a continuous flow reaction system over a period of 30 h. In addition to assessing the effect of the composition of the catalytic support, the influence of the temperature (200-260 °C), NaOH/glycerol molar ratio (0.5-1.

Metal-organic frameworks as template for synthesis of Mn/Mn mixed valence manganese cobaltites electrocatalysts for oxygen evolution reaction.

Cobalt-based oxides are among the most promising electrocatalysts for oxygen evolution reactions (OER). In this context, this work reports the synthesis of manganese-doped cobaltites using the Zeolitic-Imidazolate Frameworks 67 (ZIF-67) as template. The incorporation of manganese ions into ZIF-67 structure was evaluated in ethanol and methanol, in order to obtain the best synthetic route.

Improved mechanical performance of self-adhesive resin cement filled with hybrid nanofibers-embedded with niobium pentoxide.

Objectives: In this study hybrid nanofibers embedded with niobium pentoxide (NbO) were synthesized, incorporated in self-adhesive resin cement, and their influence on physical-properties was evaluated.

Methods: Poly(D,L-lactide), PDLLA cotton-wool-like nanofibers with and without silica-based sol-gel precursors were formulated and spun into submicron fibers via solution blow spinning, a rapid fiber forming technology. The morphology, chemical composition and thermal properties of the spun fibers were characterized by field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS) and Fourier-transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC), respectively.

1D hollow MFeO (M = Cu, Co, Ni) fibers by Solution Blow Spinning for oxygen evolution reaction.

The development of low-cost transition metal electrocatalysts for the oxygen evolution reaction (OER) has been the focus of intense research. Herein, we report for the first time the synthesis of one dimensional (1D) hollow MFeO (M = Cu, Co and Ni) fibers by the Solution Blow Spinning (SBS) technique and their performance towards OER in alkaline medium. The formation mechanism of the hollow structure and the influence of the fibrillar morphology on the performance of electrocatalysts were discussed.

Evidence for the dissolution of molybdenum during tribocorrosion of CoCrMo hip implants in the presence of serum protein.

Unlabelled: We have characterized CoCrMo, Metal-on-Metal (MoM) implant, wear debris particles and their dissolution following cycling in a hip simulator, and have related the results to the tribocorrosion of synthetic wear debris produced by milling CoCrMo powders in solutions representative of environments in the human body. Importantly, we have employed a modified ICP-MS sample preparation procedure to measure the release of ions from CoCrMo alloys during wear simulation in different media; this involved use of nano-porous ultrafilters which allowed complete separation of particles from free ions and complexes in solution. As a result, we present a new perspective on the release of metal ions and formation of metal complexes from CoCrMo implants.