Enhancement of the ionic conductivity and reduction of diffusion barriers of lithium-ion batteries are crucial for improving the performance of the fast-growing energy storage devices. Recently, the fast-charging capability of commercial-like lithium-ion anodes with the smallest modification of the current manufacturing technology has been of great interest. We used first principles methods computations with density functional theory and the climbing image-nudged elastic band method to evaluate the impact of an external electric field on the stability, electronic band gap, ionic conductivity, and lithium-ion diffusion coefficient of penta-graphene nanoribbons upon lithium adsorption.
View Article and Find Full Text PDFIn this report, we introduce a novel idea to prepare a redox additive in a gel polymer electrolyte system of PVA-ZnSO-HSO based on zinc-carbon battery recycling. Here, zinc cans from spent zinc-carbon batteries are dissolved completely in 1 M HSO to obtain a redox additive in an aqueous electrolyte of ZnSO-HSO. Moreover, carbon nanoparticles and graphene nanosheets were synthesized from carbon rod and carbon powder from spent zinc-carbon batteries by only one step of washing and electrochemical exfoliation, respectively, which have good electrochemical capability.
View Article and Find Full Text PDFIn this paper, carbon materials, including graphene nanosheets and carbon nanoparticles, were prepared from spent zinc-carbon batteries by the following two simple methods: electrochemical exfoliation and ultrasonication. Here, graphene nanosheets were synthesized by electrochemical exfoliation in 0.5 M HSO by using a direct current power supply with two carbon rods from spent zinc-carbon batteries.
View Article and Find Full Text PDFAll-solid-state lithium batteries (ASSLBs) using solid polymer electrolytes (SPEs) are believed to be future next-generation batteries aiming to replace high-risk traditional batteries using liquid electrolytes, which have a wide application range in portable electronic devices, portable power supplies, and especially in electric vehicles. Moreover, the appearance of SPEs can overcome the electrolyte leakage and flammability problems in conventional lithium-ion batteries. Nevertheless, ASSLBs still face some limitations due to the low ionic conductivity of solid-state electrolytes (SSEs) at room temperature and the poor contact electrode/electrolyte interface, which can be solved by suitable strategies.
View Article and Find Full Text PDFHydrogen is the most environmentally friendly and cleanest fuel that has the potential to supply most of the world's energy in the future, replacing the present fossil fuel-based energy infrastructure. Hydrogen is expected to solve the problem of energy shortages in the near future, especially in complex geographical areas (hills, arid plateaus, ) and harsh climates (desert, ice, ). Thus, in this report, we present a current status of achievable hydrogen fuel based on various scopes, including production methods, storage and transportation techniques, the global market, and the future outlook.
View Article and Find Full Text PDFHerein, for the first time, we present two-dimensional (2D) NHVO nanoflakes as an excellent material for both energy conversion of the hydrogen evolution reaction and storage of supercapacitors by a simple and fast two-step synthesis, which exhibit a completely sheet-like morphology, high crystallinity, good specific surface area, and also stability, as determined by thermogravimetric analysis. The 2D-NHVO flakes show an acceptable hydrogen evolution performance in 0.5 M HSO on a glassy carbon electrode (GCE) coated with 2D-NHVO, which results in a low overpotential of 314 mV at -10 mA cm with an excellent Tafel slope as low as 90 mV dec.
View Article and Find Full Text PDFIn this study, we provide a simple and green approach to recycle waste zinc carbon batteries for making carbon dots and porous carbon material. The carbon dots are easily synthesized by one green step, the hydrothermal treatment of a carbon rod in a mixture of DI water and pure ethanol to obtain a blue fluorescence under UV light, which can be used directly as a fluorescence ink. The as-prepared carbon dot process give typical dots with a uniform diameter from 3 to 8 nm with a strong slight blue fluorescent.
View Article and Find Full Text PDFThe aim of this study is to prepare a two-dimensional (2D) WO·HO nanostructure assembly into a flower shape with good chemical stability for electrochemical studies of catalyst and energy storage applications. The 2D-WO·HO nanoflowers structure is created by a fast and simple process at room condition. This cost-effective and scalable technique to obtain 2D-WO·HO nanoflowers illustrates two attractive applications of electrochemical capacitor with an excellent energy density value of 25.
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