A new lignan from the flowers of L. (Malvaceae).

From MeOH-soluble fraction of the flowers of (Malvaceae), one new lignan, (+)-4--methyl-5'-methoxy-secoisolariciresinol (), together with four known compounds (-) were isolated. The structures were elucidated based on NMR spectroscopic analysis. The absolute configuration of was determined based on the Cotton effects in the CD spectrum.

Diverse Electronic and Magnetic Properties of Chlorination-Related Graphene Nanoribbons.

The dramatic changes in electronic and magnetic properties are investigated using the first-principles calculations for halogen(X: Cl, Br, I, At)-adsorbed graphene nanoribbons. The rich and unique features are clearly revealed in the atoms-dominated electronic band structures, spin arrangement/magnetic moment, spatial charge distribution, and orbital- and spin-projected density of states. Halogen adsorptions can create the non-magnetic, ferromagnetic or anti-ferromagnetic metals, being mainly determined by concentrations and edge structures.

Subcaliber discarding sabot airgun projectiles.

Medical literature abounds with reports on injuries and fatalities caused by airgun projectiles. While round balls or diabolo pellets have been the standard projectiles for airguns for decades, today, there are a large number of different airgun projectiles available. A very uncommon--and until now unique--discarding sabot airgun projectile (Sussex Sabo Bullet) was introduced into the market in the 1980s.

Ballistic parameters of .177 (4.5 mm) caliber plastic-sleeved composite projectiles compared to conventional lead pellets.

The capability of conventional air gun lead pellets (diabolo pellets) to cause severe injuries or fatalities even at low kinetic energy levels is well documented in medical literature. Modern composite hunting pellets, usually a metal core (made of steel, lead, zinc, or a zinc and aluminum alloy) encased in a plastic sleeve, are of special forensic and traumatological interest. These projectiles are advertised by the manufacturers to discharge at higher velocities than conventional air gun pellets, thus generating very high tissue-penetrating capabilities.

pH sensing characteristics and biosensing application of solution-gated reduced graphene oxide field-effect transistors.

Solution-gated reduced graphene oxide field-effect transistors (R-GO FETs) were investigated for pH sensing and biochemical sensing applications. A channel of a networked R-GO film formed by self-assembly was incorporated as a sensing layer into a solution-gated FET structure for pH sensing and the detection of acetylcholine (Ach), which is a neurotransmitter in the nerve system, through enzymatic reactions. The fabricated R-GO FET was sensitive to protons (H(+)) with a pH sensitivity of 29 mV/pH in terms of the shift of the charge neutrality point (CNP), which is attributed to changes in the surface potential caused by the interaction of protons with OH surface functional groups present on the R-GO surface.