The purpose of this work was to develop, characterize and test new low-cost materials suitable for removing methylene blue dye from water and wastewater by adsorption. The solid materials consisted of silica gel powder (SG), silica gel mixed with eggshell powder (SG-ES) and a mixture of silica gel with sand from the western Iraqi desert (SG-SI). The samples were milled by using an electrical mixer and a ball mill, followed by a drying step.
View Article and Find Full Text PDFThe aim of this study was to recover Sc as the main product and Fe as a by-product from Hungarian bauxite residue/red mud (RM) waste material by solvent extraction (SX). Moreover, a new technique was developed for the selective separation of Sc and Fe from real RM leachates. The presence of high Fe content (∼38%) in RM makes it difficult to recover Sc because of the similarity of their physicochemical properties.
View Article and Find Full Text PDFMultiwalled carbon nanotubes (MWCNTs) were oxidized using a mixture of HSO and HNO, and the oxidized MWCNTS were decorated with magnetite (FeO). Finally, poly-N-isopropyl acrylamide-co-butyl acrylate (P-NIPAM) was added to obtain P-NIPAM/Fe/MWCNT nanocomposites. The nanosorbents were characterized by various techniques, including X-ray diffraction, transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis, and Brunauer-Emmett-Teller analysis.
View Article and Find Full Text PDFThe recovery of scandium (Sc) from wastes and various resources using solvent extraction (SX) was discussed in detail. Moreover, the metallurgical extractive procedures for Sc recovery were presented. Acidic and neutral organophosphorus (OPCs) extractants are the most extensively used in industrial activities, considering that they provide the highest extraction efficiency of any of the valuable components.
View Article and Find Full Text PDFIn this paper, the application of multiwalled carbon nanotubes (MWCNTs) based on metal oxide nanocomposites as adsorbents for the removal of hydrocarbons such as kerosene from water was investigated. Functionalized MWCNTs were obtained by chemical oxidation using concentrated sulfuric and nitric acids. VO, CeO and VO:CeO nanocomposites were prepared using the hydrothermal method followed by deposition of these oxides over MWCNTs.
View Article and Find Full Text PDFIn this study, a nano-adsorbent was prepared for kerosene removal from water. Multiwalled carbon nanotubes (MWCNTs) were functionalized with concentrated HNO (nitric acid). Subsequently, FeO (magnetite) nanoparticles were deposited on the MWCNTs to prepare a magnetite/MWCNTs (Fe-MWCNTs) nanocomposite.
View Article and Find Full Text PDFIn this research, multi-walled carbon nanotubes (MWCNTs) were functionalized by oxidation with strong acids HNO, HSO, and HO. Then, magnetite/MWCNTs nanocomposites were prepared and polystyrene was added to prepare polystyrene/MWCNTs/magnetite (PS:MWCNTs:Fe) nanocomposites. The magnetic property of the prepared nano-adsorbent PS:MWCNTs:Fe was successfully checked.
View Article and Find Full Text PDFThe aim of this study was to prepare novel supramolecular hybrid nanoparticles (HNPs) that can selectively separate and recover scandium metal ions, Sc(III), from an aqueous phase based on molecular recognition technology (MRT). Moreover, this approach is fully compatible with green chemistry principles. In this work, natural amorphous silica (SiO) nanoparticles were prepared by a precipitation method from Iraqi rice husk (RH) followed by surface modification with 3-amino-propyl triethoxysilane (APTES) as coupling agent and Kryptofix 2.
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