Hydrogen spillover helps create defects and oxygen vacancies in TiO crystals, enhancing electron conductivity and visible light absorption.
Crystal facet engineering improves photocatalytic activity by reducing recombination of photogenerated electrons and holes.
Rutile TiO nanorods with varying aspect ratios were synthesized, with the Pt-deposited ones showing the best performance for visible light-driven H production due to the combined effects of Ti defects and effective charge separation.
The first direct observation of a platinum cluster (Pt4) has shown that it can randomly change between different structures, known as isomers.
Researchers used advanced microscopy techniques to achieve super high-resolution imaging, capturing the atomic positions of the cluster at nearly atomic scale and at very short time intervals (0.2 seconds).
The data collected indicates that the process of isomerization for the Pt4 cluster follows a straightforward first-order kinetic model, meaning the rate of change is predictable and depends on the concentration of the cluster.