Spin-crossover in iron(ii)-Schiff base complexes.

The spin-crossover (SCO) phenomenon is one of the most prominent examples of bi-stability in molecular chemistry, and the SCO complexes are proposed for nanotechnological applications such as memory units, sensors, and displays. Since the discovery of the SCO phenomenon in tris(N,N-dialkyldithiocarbamato)iron(iii) complexes, numerous investigations have been made to obtain bi-stable SCO complexes undergoing spin-state switching at or around room temperature (RT). Valiant efforts have also been made to elucidate the structure-property relationship in SCO complexes to understand the factors-such as ligand-field strength, molecular geometry, and intermolecular interactions-governing the SCO.

Recent advances in and potential utilities of paper-based electrochemical sensors: beyond qualitative analysis.

Paper-based electrochemical sensors (PESs) have been evidenced as analytical strategies for employing simple, low-cost, portable and disposable sensing platforms that can be used in many application areas. Recently, PESs have gained extensive attention because of their advantages of advanced sensitivity and selectivity during detection provided by electrochemistry, compared with microfluidic paper-based analytical devices (μPADs) that still lack these advantages. Also, it can be expected that PESs can better meet current user demands, making them a stand-out analytical tool because of their capability for multiple analyte detection and their compatibility in a variety of application areas, like clinical diagnosis, environmental monitoring and food quality control.