All-Solid-State Reference Electrode with Heterogeneous Membrane.

Novel reference electrodes with a solid contact coated by a heterogeneous polymer membrane are described. The electrodes are obtained using Ag nanoparticles, AgBr, KBr suspended in tetrahydrofuran solution of PVC and DOS and deposited on Ag substrate, or another substrate covered with Ag, by drop casting. After a short period of soaking in a KBr solution, stable and reproducible formal potentials of -157 ± 2 mV (vs Ag/AgCl/3 M KCl) were observed, and the solid-contact reference electrodes were ready to use.

Galvanic cell without liquid junction for potentiometric determination of copper.

This paper describes potentiometric measurements in an integrated galvanic cell with both indicator and reference electrodes. Both electrodes are conducting polymer-based. The copper-sensitive indicator electrode is made by using poly(3,4-ethylenedioxythiophene) (PEDOT) doped with 2-(o-arsenophenylazo)-1,8-dihydroxynaphthalene-3,6-disulphonic sodium salt (Arsenazo-I) as the electroactive substance in the film, while the reference electrode is based on PEDOT doped by 2-morpholineoethanesulfonic acid (MES).

Conducting polymers in modelling transient potential of biological membranes.

The possibility of using conducting polymer (CP) films doped with biological ligands as artificial biological membranes to study potential formation mechanisms is presented. Calcium and magnesium ion-binding anionic sites--asparagine, glutamine, adenosinotriphosphate and heparin are incorporated into the poly(pyrrole) film during electrochemical polymerization. This approach allows the competitive calcium-magnesium ion-exchange to be inspected by open circuit measurements.

Junction-less reference electrode for potentiometric measurements obtained by buffering pH in a conducting polymer matrix.

A reference electrode for potentiometric measurements based on conducting polymers (CP) doped with pH buffering ligands is described. Both the CPs and doping ligands are selected and adjusted in such a way that possible ionic and redox sensitivity is hampered, while the pH buffering property of the CP film is exposed. In this way, the electric potential drop at the conducting polymer|solution interface is stabilized and close to constant over a certain pH range.