Construction of an Interfacial Photocatalytic Mode Based on Carbonized Mushrooms to Enhance Infrared Light-Assisted Photocatalytic Water Splitting Performance.

To find a more efficient way to generate photocatalytic hydrogen, we developed the interfacial photocatalytic mode, in which the photocatalytic reaction can be transferred to a high-energy interfacial area. The new interfacial mode in this work is assembled with the help of carbonized mushrooms, which is an ideal water transporter as well as an excellent photothermal converter. The higher temperature from efficient light-to-heat conversion performance and thermal localization promote the efficiency of hydrogen evolution, and some effects peculiar to the interfacial mode can make the departure of hydrogen from the active sites of the photocatalyst smoother.

Interfacial Design to Enhance Photocatalytic Hydrogen Evolution via Optimizing Energy and Mass Flows.

Energy and mass transfer in photocatalytic systems plays a significant role in photocatalytic water splitting, but relevant research has long been ignored. Here, an interfacial photocatalytic mode for photocatalytic hydrogen production is exploited to optimize the energy and mass flows and mainly includes a heat-insulating layer, a water-channel layer, and a photothermal photocatalytic layer. In this mode, the energy flow is optimized for efficient spreading, conversion, and utilization.