Enhanced dielectric losses in α-MnO protonation modulation.

MnO octahedra without distortions in α-MnO have a low dipole content, which limits their dielectric loss capabilities. Herein, we develop protonated MnO with distorted MnO octahedra for increased dipole numbers a two-step hydrothermal method. In comparison with α-MnO, this protonated MnO provides greatly improved dipole polarization loss capabilities, resulting in a reflection loss value of -19.

Harnessing Pseudo-Jahn-Teller Disordering of Monoclinic Birnessite for Excited Interfacial Polarization and Local Magnetic Domains.

The symmetry in a polymorph is one of the most important elements for determining the inherent lattice nature. The MnO host tends to high-symmetry MnO octahedra as a result of the electronic structure t e of Mn ions, displaying an ordered structure accompanying with poor polarization loss and limiting its application toward high-performance microwave absorbers. Here, a pseudo-Jahn-Teller (PJT) distortion and PJT disordering design with abundant self-forming interfaces and local magnetic domains in the monoclinic birnessite-MnO host is first reported.