This study introduces a flexible and scalable charge-trapping intermediate layer of conjugated polymeric film comprising [PANI/PEDOT:PSS] between the [PVA/PDDA] triboelectric layer and graphene-based [PVA/GNP-PSS] electrode using the layer-by-layer (LbL) assembly method. By varying the deposition layers, the optimal coating layout was identified as 2 and 8 bilayers of intermediate and triboelectric layers, respectively. The triboelectric nanogenerator (TENG) fabricated with this optimal configuration achieved peak output voltage and current of 180 V and 9 μA, respectively, at 3 Hz and 5 N against PDMS.
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