Adsorption of Ions at Uncharged Insoluble Monolayers.

A method is proposed for the experimental determination of the adsorption of inorganic electrolytes at a surface covered with insoluble surfactant monolayer. This task is complicated by the fact that the change of the salt concentration alters both chemical potentials of the electrolyte and the surfactant. Our method resolves the question by combining data for the surface pressure versus area of the monolayer at several salt concentrations with data for the equilibrium spreading pressure of crystals of the surfactant (used to fix a standard state).

Adsorption of ions at the interface oil|aqueous electrolyte and at interfaces with adsorbed alcohol.

We investigate the applicability of the Schmutzer's model for three types of interfaces: aqueous electrolyte|alkane, aqueous electrolyte|long chained alcohol phase, and aqueous electrolyte|alkane with adsorbed alcohol. The model predicts a strong decrease of the electrolyte desorption at water|alcohol interface in comparison with water|alkane, in quantitative agreement with the tensiometric data. The effect is related to the penetration of the alcohol -OH group into the surface layer of the aqueous solution.

Surface tension and surface Δχ-potential of concentrated Z+:Z- electrolyte solutions.

Schmutzer's model for the surface of aqueous electrolyte solutions is generalized to Z+:Z- salts. The thickness of the ion-free layer is calculated from the thickness of the "hydrophobic gap" at the water surface (1.38Å) and the radii of the ionic hydration shells.