Publications by authors named "Tatsuya Kawabata"
Article Synopsis
- A new method has been developed for creating chiral organozinc intermediates using iron catalysis and azabicycloalkenes in an enantioselective carbometalation reaction.
- The study shows how chiral phosphine ligands directly coordinate with iron during the reaction process, influencing the formation of bonds.
- This innovative iron-catalyzed reaction is expected to aid in the synthesis of biologically active compounds.
Non-protected halohydrins are cross-coupled with aryl aluminium reagents to produce aryl alkanols in the presence of the iron-bisphosphine catalysts. Remarkable reaction rate enhancement and diastereoinduction are realized by the in situ generated aluminium alkoxides, offering a new method for the reactivity and selectivity control of the iron-catalysed cross-coupling reaction.
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