A simple two step synthetic method for di-doped crystalline mesoporous tin dioxide powder containing antimony and fluoride at ambient pressure and temperature has been developed. This approach produced materials with high surface areas and improved electrical and optoelectrical conductance. The two dopant elements; antimony and fluoride were introduced to tin dioxide by two approaches.
View Article and Find Full Text PDFWe report the successful one pot synthesis of crystalline mesoporous tin dioxide powder doped with fluoride at ambient pressure and temperature. This material possesses a high surface area, narrow pore size distribution, small average crystallite sizes, and good opto-electrical properties. The existence of fluorine increased the opto-electronic activity of tin dioxide by 20 times, and conductivity by 100 times compared with pristine tin dioxide prepared via the same method.
View Article and Find Full Text PDFWe report the successful direct synthesis of an ultrastable mesoporous silicon dioxide framework containing silver nanoclusters using a modified true liquid crystal templating method. Our modification produced an extraordinary material with a high average Brunauer-Emmett-Teller specific surface area of 1785 m g - the highest reported surface area to date - and an ultrastable mesoporous structure, which has been stable for nine years so far. This method eliminates the need for reduction of silver oxide into metallic silver and restricts the growth of silver clusters.
View Article and Find Full Text PDFSnO is one of the most studied oxide materials for gas sensing applications. Investigations have shown that SnO is sensitive to a wide range of gaseous compounds. However, its lack of selectivity remains an issue.
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