Small-scale medical oxygen production unit using PSA technology: modeling and sensitivity analysis.

This study presents a solid approach for small-scale medical oxygen production unit using pressure swing adsorption (PSA) technology. The objective of this research is to develop a mathematical model and conduct a sensitivity analysis to optimise the design and operating parameters of the PSA system. Based on the simulation results, an optimal set of operational parameter values has been obtained for the PSA beds.

Engineering g-CN with CuAl-layered double hydroxide in 2D/2D heterostructures for visible-light water splitting.

CuAl layered double hydroxide (LDH) and polymeric carbon nitride (g-CN, GCNN) were assembled to construct a set of novel 2D/2D CuAl-LDH/GCNN heterostructures. These materials were tested towards H and O generation from water splitting using visible-light irradiation. Compared to pristine materials, the heterostructures displayed strongly enhanced visible-light H evolution, dependent on the LDH content, which acts as a cocatalyst, replacing the benchmark Pt.

Intrinsic catalytic properties of extruded clay honeycomb monolith toward complete oxidation of air pollutants.

The present work highlights the intrinsic catalytic properties of extruded clay honeycomb monolith toward complete oxidation of various air pollutants namely CO, methane, propane, acetylene, propene, n-butene, methanol, ethanol, n-propanol, n-butanol, acetone, dimethyl ether, benzene, toluene, o-xylene, monochlorobenzene and 1,2-dichlorobenzene. Total catalytic conversion was achieved for all tested compounds with different behaviors depending on pollutants' structural and chemical nature. The comparison of T50 values obtained from light-off curves allowed the establishment of the following reactivity sequence: ketone>alcohol>ether>CO>alkyne>aromatic>alkene>chlorinated aromatic>alkane.

Evaluation of the potential of volatile organic compound (di-methyl benzene) removal using adsorption on natural minerals compared to commercial oxides.

This study is dedicated to the investigation of the potential of volatile organic compounds (VOC) adsorption over low cost natural minerals (bentonite and diatomite). The performances of these solids, in terms of adsorption/desorption properties, were compared to commercial adsorbents, such as silica, alumina and titanium dioxide. The solids were first characterized by different physico-chemical methods and di-methyl benzene (dMB) was selected as model VOC pollutant for the investigation of adsorptive characteristics.

A comparative study of the adsorption and desorption of o-xylene onto bentonite clay and alumina.

In this paper, adsorptive performance of natural clay of bentonite type has been investigated as a potential VOC adsorbent on the basis its promising physical-chemical and morphological properties which were compared to commercial gamma-Al(2)O(3) solid. The vapour-solid adsorption isotherms of xylene were measured at different temperatures ranging from 300 to 373 K using dynamical method and the obtained data confronted to classical models such as Langmuir and Freundlich. On the other hand, the solids physico-chemical characteristics and adsorptive performances were correlated to some cost aspects because of their importance for design and engineering of adsorption plant.