Despite the critical role of balanced nutrition in crop productivity, the use of potash (K) and zinc (Zn) is not much practiced by Pakistani farmers. The reduced nutrient uptake and crop productivity together increase the costs associated with fertilization and revisit farmers' confidence in the efficacy and profitability of fertilizers. To address this problem, a field study was conducted in the research area of the MNS-University of Agriculture, Multan, in collaboration with Engro Fertilizers Limited.
View Article and Find Full Text PDFThis research paper proposes a novel approach for constructing substitution boxes (S-boxes) over Gaussian integers, which are complex numbers with integer coefficients. The proposed method is based on the properties of the Gaussian integers and their arithmetic operations and ensures the S-boxes exhibit strong cryptographic properties. Furthermore, the paper demonstrates how these S-boxes can be utilized for image encryption through a substitution-permutation network (SPN) over Gaussian integers.
View Article and Find Full Text PDFA woman in her 20s, who was pregnant, underwent a routine antenatal ultrasound revealing organised intraventricular haemorrhage and a vascular area in the left thalamic region. Fetal MRI raised suspicion of arteriovenous malformation (AVM). The baby was delivered at 36 weeks via C-section, and initial brain MRI suggested a possible neoplastic lesion.
View Article and Find Full Text PDFApplication of organic residues such as farm manure and biochar in various agricultural environments have shown positive effects on soil carbon sequestration. However, there is a lack of consensus regarding the agronomical benefits of a single and small dose of biochar and farm manure in arid alkaline soils. Therefore, a field experiment with the given treatments (1) control (no amendment), (2) acidified manure (AM) at 300 kg ha, (3) nitrogen (N) enriched biochar (NeB) at 3 Mg ha, and (4) an equal combination of AM + NeB (150 kg ha AM + 1.
View Article and Find Full Text PDFA nano-micro heterostructure has been established to address the challenges of selectivity, stress, pitting corrosion, and long-term durability of anodes in unpurified seawater. The heterostructure comprised NiOOH nanosheets embedded within a high surface area Ni(OH) microarray, and the surface structure is further functionalized with sulfate (SO). This cation-selective protective layer impedes chloride (Cl) diffusion and abstracts H from reaction intermediates, leading to enhanced selectivity and corrosion resistance of the anode.
View Article and Find Full Text PDFFracture and migration of port-a-catheter, following long term access into the central venous vasculature is a rare clinical scenario. The consequences of fracture and migration includes fragmented device relocating into the right atrium or ventricle, eventually causing life threatening complications such as arrhythmias, pseudoaneurysms, perforations or very rarely embolization. We report a case of a 67-year-old female with a broken port-a-catheter which had been placed initially for chemotherapy for bilateral breast cancer.
View Article and Find Full Text PDFBackground: Though various computerized tomography (CT) severity scores have been described for risk prognostication for coronavirus disease 2019 (COVID-19), most are challenging to calculate and have variable inter-observer agreement. The objective of this study was to develop a simple CT severity score (CT-SS) with good inter-observer agreement and assess its correlation with clinical outcome.
Methods: This retrospective study was conducted at the Aga Khan University Hospital (AKUH), from April-August 2020.
ACS Appl Mater Interfaces
May 2022
The accomplishment of seawater electrolysis to produce green hydrogen energy needs an efficient and durable electrocatalyst with high selectivity and corrosion resistance. Here we report a free-standing amorphous nanostructured oxygen evolution reaction (OER) electrocatalyst with microvoids developed by embedding Gd-doped MnO nanosheets in a CuO-Cu(OH) nanostructure array (Gd-MnO@ CuO-Cu(OH). The surface oxygen vacancies modulated the electronic structure of the catalyst and offered active sites with optimal chemisorption energy to OER intermediates.
View Article and Find Full Text PDFPhotocatalytic water splitting is considered one of the most important and appealing approaches for the production of green H to address the global energy demand. The utmost possible form of artificial photosynthesis is a two-step photoexcitation known as "Z-scheme", which mimics the natural photosystem. This process solely relies on the effective coupling and suitable band positions of semiconductors (SCs) and redox mediators for the purpose to catalyze the surface chemical reactions and significantly deter the backward reaction.
View Article and Find Full Text PDFObjective: To assess the outcome of endovascular treatment of intracranial aneurysm over 15 years.
Methods: The retrospective study was conducted at the at Radiology Department of Aga Khan University Hospital, Karachi, and comprised medical records from April 2003 to April 2018 of patients who received endovascular treatment for intracranial aneurysm. Multiple variables reviewed included demographics, clinical presentation, aneurysm morphology, technique used, technique outcome and clinical outcome.
Management of endogenous Cushing syndrome is based on its aetiology. Increased Adrenocorticotropic Hormone (ACTH) levels are the most common cause of this disorder and, therefore, it is critical to determine the source of ACTH before further management. Dynamic post contrast MRI is currently the most common investigation implied to diagnose pituitary adenoma; however, it comes with the drawback of low specificity and high false positive results.
View Article and Find Full Text PDFObjective The goal of this study was to compare the efficacy of tramadol and paroxetine in the treatment of primary premature ejaculation (PE). Study design This study was a randomized controlled trial performed in the outpatient department of Nishtar Hospital, Multan, from January 2017 to January 2018. Methodology One hundred six patients were diagnosed with PE and included in the study.
View Article and Find Full Text PDFPolarization converters play an important role in modern communication systems, but their wide and multiple band operation to facilitate volume and size reduction is quite challenging. In this paper, a triple-band Linear Polarization to Circular Polarization (LP-to-CP) converter is presented using a novel design procedure based on geometric parameters optimization of a metasheet. The proposed converter is ultrathin, wideband, stable over a wide range of incident angles, and polarization diverse.
View Article and Find Full Text PDFBackground: During a preliminary study, effects of 0, 20, 40, and 60 mM NaCl salinity were assessed on germination rate in relation to electrolyte leakage (EL) in sweet pepper. Results explored significant rises in ethylene evolution from seeds having more EL. It was, therefore, hypothesized that excessive ethylene biosynthesis in plants due to salinity stress might be a root cause of low crop productivity.
View Article and Find Full Text PDFThis paper presents a new shape (s-shape monopole) of a super wideband antenna using stepped meander lines, a quarter waveguide transformer feeding line, and a defected ground structure (DGS). The antenna will be used for multiple wireless communication applications like WIMAX/WLAN/ISM/UWB, and also for several wireless communication applications. The total dimensions of the proposed antenna are 35 mm × 35 mm × 1.
View Article and Find Full Text PDFThe use of water splitting modules is highly desired for the sustainable production of H as a future energy carrier. However, the sluggish kinetics and demand of high anodic potential are the bottlenecks for half-the cell oxygen evolution reaction (OER), which severely hamper the overall conversion efficiency. Although transition metal oxides based electrocatalysts have been envisioned as cost-effective and potential contenders for this quest, nevertheless, their low conductivity, instability, and limited number of active sites are among the common impediments that need to be addressed to eventually enhance their inherent catalytic potential for enhanced OER activity.
View Article and Find Full Text PDFThe paper presents a highly efficient, low cost, ultra-wideband, microstrip monopole antenna for microwave imaging and wireless communications applications. A new structure (z-shape, ultra-wideband (UWB) monopole) is designed, which consists of stepped meander lines to achieve super-wide bandwidth and high efficiency. Three steps are used to design the proposed structure for the purpose to achieve high efficiency and wide bandwidth.
View Article and Find Full Text PDFMetal nanoclusters (NCs, size ≤2 nm) are emerging materials in catalysis owing to their unique catalytic and electronic properties such as high surface/volume ratio, high redox potential, plethora of surface active sites, and dynamic behavior on a suitable support during catalysis. Herein, in situ growth of ultrasmall and robust Co@β-Co(OH) NCs (≈2 nm) hosted in a honeycomb-like 3D N-enriched carbon network was developed for water-oxidation catalysis with extremely small onset potential (1.44 V).
View Article and Find Full Text PDFSoil salinity is a major constraint for the global agricultural production. For many decades, Na exclusion from uptake has been the key trait targeted in breeding programs; yet, no major breakthrough in creating salt-tolerant germplasm was achieved. In this work, we have combined the microelectrode ion flux estimation (MIFE) technique for non-invasive ion flux measurements with confocal fluorescence dye imaging technique to screen 45 accessions of barley to reveal the relative contribution of Na exclusion from the cytosol to the apoplast and its vacuolar sequestration in the root apex, for the overall salinity stress tolerance.
View Article and Find Full Text PDFIn this paper, complementary metamaterial sensor is designed for nondestructive evaluation of dielectric substrates. The design concept is based on electromagnetic stored energy in the complementary circular spiral resonator (CCSR), which is concentrated in small volume near the host substrate at resonance. This energy can be employed to detect various electromagnetic properties of materials under test (MUT).
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