Characterization and potential usage of selected eggshell species.

Today's awareness of environmental pollution and the idea of creating a reuse area for waste is one of the trend topics. The base opinion, regarding the reuse of any material is that all resources are inherently limited in the world. In the ethical approach, it is a moral issue that people take responsibility for future generations to protect nature.

DFT, FT-Raman and FT-IR investigations of 5-o-tolyl-2-pentene.

FT-IR and Raman spectra of 5-o-tolyl-2-pentene (OTP) have been experimentally reported in the region of 4000-10 cm(-1) and 4000-100 cm(-1), respectively. The optimized geometric parameters, normal mode frequencies and corresponding vibrational assignments of cis and trans isomers of OTP (C12H16) have been theoretically examined by means of B3LYP hybrid density functional theory (DFT) method together with 6-31G(d) and 6-31++G(d,p) basis sets. Furthermore, reliable vibrational assignments have made on the basis of potential energy distribution (PED) calculated.