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View Article and Find Full Text PDFMost lithium-ion capacitor (LIC) devices include graphite or non-porous hard carbon as negative electrode often failing when demanding high energy at high power densities. Herein, we introduce a new LIC formed by the assembly of polymer derived hollow carbon spheres (HCS) and a superactivated carbon (AC), as negative and positive electrodes, respectively. The hollow microstructure of HCS and the ultra large specific surface area of AC maximize lithium insertion/diffusion and ions adsorption in each of the electrodes, leading to individual remarkable capacity values and rate performances.
View Article and Find Full Text PDFPorous carbons were prepared from a metal-organic framework (MOF, named ZIF-8), with or without modification, via high-temperature pyrolysis. Porous carbons with high nitrogen content were obtained from the calcination of MOF after introducing an ionic liquid (IL) (IL@MOF) via the ship-in-bottle method. The MOF-derived carbons (MDCs) and IL@MOF-derived carbons (IMDCs) were characterized using various techniques and used for liquid-phase adsorptions in both water and hydrocarbon to understand the possible applications in purification of water and fuel, respectively.
View Article and Find Full Text PDFIn recent years, graphene-based materials have been in the forefront as electrode material for electrochemical energy generation and storage. Despite this prevalent interest, synthesis procedures have not attained three important efficiency requirements, that is, cost, energy, and eco-friendliness. In this regard, in the present work, graphene nanoplatelets with selectively functionalized edges (XGnPs) are prepared through a simple, eco-friendly and efficient method, which involves ball milling of graphite in the presence of hydrogen (H2), bromine (Br2), and iodine (I2).
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