A 3.0 µm Pixels and 1.5 µm Pixels Combined Complementary Metal-Oxide Semiconductor Image Sensor for High Dynamic Range Vision beyond 106 dB.

We propose a new concept image sensor suitable for viewing and sensing applications. This is a report of a CMOS image sensor with a pixel architecture consisting of a 1.5 μm pixel with four-floating-diffusions-shared pixel structures and a 3.

Electronic and vibrational structures in the S and S states of coronene.

We observed the fluorescence excitation spectra and dispersed fluorescence spectra of jet-cooled coronene-h and coronene-d. We analyzed the vibronic structures, assuming a planar and sixfold symmetric molecular structure (D). The S state was identified to be B2u1.

Spectroscopic study on deuterated benzenes. III. Vibronic structure and dynamics in the S(1) state.

We observed the fluorescence excitation spectra and mass-selected resonance enhanced multiphoton ionization (REMPI) excitation spectra for the 6(0)(1), 6(0)(1)1(0)(1), and 6(0)(1)1(0)(2) bands of the S1←S0 transition of jet-cooled deuterated benzene and assigned the vibronic bands of C6D6 and C6HD5. The 6(0)(1)1(0)(n) (n = 0, 1, 2) and 0(0)(0) transition energies were found to be dependent only on the number of D atoms (ND), which was reflected by the zero-point energy of each H/D isotopomer. In some isotopomers some bands, such as those of out-of-plane vibrations mixed with 6(1)1(n), make the spectra complex.

S1 and S2 states of linear and zigzag cata-condensed hydrocarbons.

We investigated the S1 and S2 states of linear and zigzag cata-condensed hydrocarbons on the basis of the results of jet spectroscopy and theoretical calculations. The S1 states of anthracene and tetracene are represented by the HOMO → LUMO configuration (Φ(A)), whereas those of phenanthrene and chrysene are represented by HOMO-1 → LUMO and HOMO → LUMO+1 configurations (Φ(B)). We found that the fluorescence lifetime varied with different vibronic levels in the S1 states of linear cata-condensed hydrocarbons due to the mode-selective internal conversion to the S0 state.

Jet spectroscopy of buckybowl: electronic and vibrational structures in the S0 and S1 states of triphenylene and sumanene.

Sumanene is a typical buckybowl molecule with C3v symmetry. We observed a fluorescence excitation spectrum and a dispersed fluorescence spectrum of sumanene in a supersonic jet. Bowl effects were clarified by comparing the spectra with those of triphenylene (D3h symmetry), which is a planar prototype of nonplanar sumanene.

Electronic, vibrational, and rotational structures in the S0 1A1 and S1 1A1 states of phenanthrene.

Electronic and vibrational structures in the S(0) (1)A(1) and S(1) (1)A(1) states of jet-cooled phenanthrene-h(10) and phenanthrene-d(10) were analyzed by high-resolution spectroscopy using a tunable nanosecond pulsed laser. The normal vibrational energies and molecular structures were estimated by ab initio calculations with geometry optimization in order to carry out a normal-mode analysis of observed vibronic bands. The rotational structure was analyzed by ultrahigh-resolution spectroscopy using a continuous-wave single-mode laser.

Vibrational and rotational structure and excited-state dynamics of pyrene.

Vibrational level structure in the S(0) (1)A(g) and S(1) (1)B(3u) states of pyrene was investigated through analysis of fluorescence excitation spectra and dispersed fluorescence spectra for single vibronic level excitation in a supersonic jet and through referring to the results of ab initio theoretical calculation. The vibrational energies are very similar in the both states. We found broad spectral feature in the dispersed fluorescence spectrum for single vibronic level excitation with an excess energy of 730 cm(-1).

High-resolution spectroscopy of weak and short-lived bands of the S(1) 1B(3u) <-- S(0) 1A(g) transition of naphthalene.

Rotationally resolved high-resolution spectra and fluorescence decay curves have been observed for weak and short-lived vibronic bands of the S(1) (1)B(3u) <-- S(0) (1)A(g) transition of naphthalene. Fluorescence lifetime of the vibronic band with an excess energy of 1390 cm(-1) (0(0)(0) + 1390 cm(-1) band) is remarkably shorter than that of other bands. Zeeman splitting of rotational lines is very small, so that the main radiationless process is not intersystem crossing to the triplet state but internal conversion to the ground state.

CH3 internal rotation in the S0 and S1 states of 9-methylanthracene.

Fluorescence excitation spectra and dispersed fluorescence spectra of jet-cooled 9-methylanthracene-h12 and -d12 (9MA-h12 and 9MA-d12) have been observed, and the energy levels of methyl internal rotation (CH3 torsion) in the S0 and S1 states have been analyzed. The molecular symmetry of 9MA is the same as that of toluene (G12). Because of two-fold symmetry in the pi system, the potential curve has six-fold barriers to CH3 rotation.

Vibronic structure in the S1-S0 transition of jet-cooled dibenzofuran.

Fluorescence excitation spectra of dibenzofuran in a supersonic jet are observed and the vibronic structure is analyzed for the S(1) (1)A(1) (pipi) and S(0) states. An observation of the rotational envelopes reveals that the band is a B-type band. However, it is shown that most of the strong vibronic bands are A-type bands.