Direct Observation of Palladium Leaching from Pd/C by a Simple Method: X-ray Absorption Spectroscopy of Heterogeneous Mixtures.

Herein, we show the detailed behavior of palladium leaching from palladium on charcoal by aqueous HCl, directly observed by X-ray absorption spectroscopy measurement employing a simplified reaction setup. While Pd is not affected by the addition of HCl, palladium oxide in nanoparticles readily reacts with HCl to form the ionic species [PdCl], even though these ions mostly remain adsorbed on the surface of activated charcoal and can only be detected at a low level in the solution phase. This finding provides a new aspect for control of the leaching behavior and robust usage of palladium on charcoal in organic reactions.

Meat and bone meal biochar can effectively reduce chemical fertilizer requirements for crop production and impart competitive advantages to soil.

Safe and effective circulation of nutrient-rich meat and bone meal (MBM) could become a carbon-based alternative to limited chemical fertilizers (CFs). Therefore, MBM biochars (MBMCs) were produced at 500, 800, and 1000 °C to evaluate their effects on plant growth, nutrient uptake, and soil characteristics. The results revealed that MBMC produced at 500 °C (MBMC500) contained the maximum amount of C, N, and phytoavailable P.

Heat balance analysis for self-heating torrefaction of dairy manure using a mathematical model.

A self-heating torrefaction system was developed to overcome the difficulties in converting high-moisture biomass to biochar. In self-heating torrefaction, the ventilation rate and ambient pressure must be set properly to initiate the process. However, the minimum temperature at which self-heating begins is unclear because the effects of these operating variables on the heat balance are not theoretically understood.

Improvement of the fuel properties of dairy manure by increasing the biomass-to-water ratio in hydrothermal carbonization.

There are many advantages to liquid-based hydrothermal carbonization (L-HTC) but the need to immerse the biomass in water generates more post-process water, hindering the commercialisation of HTC. To address this issue, this study investigated the feasibility of vapour-based HTC (V-HTC), which minimizes the water required. Dairy manure was hydrothermally treated at temperatures of 200, 230, 255 and 270°C and biomass-to-water ratios (B/W) of 0.

Synthesizing biochar-based fertilizer with sustained phosphorus and potassium release: Co-pyrolysis of nutrient-rich chicken manure and Ca-bentonite.

Biochar-based fertilizers (BBFs) are attracting considerable interest due to their potential to improve soil properties and the nutrient use efficiency of plants. However, a sustainable agricultural system requires decreased dependency on chemical fertilizer for BBF production and further enhancement of the slow-release performance of BBFs. In this study, we propose a simple biochar-based slow-release fertilizer synthesis technique involving the co-pyrolysis of 10 to 25% (w/w) Ca-bentonite with chicken manure as the only nutrient source (N, P, K).

Exploring the capability of mayenite (12CaO·7AlO) as hydrogen storage material.

We utilized nanoporous mayenite (12CaO·7AlO), a cost-effective material, in the hydride state (H) to explore the possibility of its use for hydrogen storage and transportation. Hydrogen desorption occurs by a simple reaction of mayenite with water, and the nanocage structure transforms into a calcium aluminate hydrate. This reaction enables easy desorption of H ions trapped in the structure, which could allow the use of this material in future portable applications.

Role of ambient pressure in self-heating torrefaction of dairy cattle manure.

This paper describes the role of ambient pressure in self-heating torrefaction of livestock manure. We explored the initiating temperatures required to cause self-heating of wet dairy cattle manure at different ambient pressures (0.1, 0.

A new torrefaction system employing spontaneous self-heating of livestock manure under elevated pressure.

This report describes a new oxidative torrefaction method employing spontaneous self-heating of feedstock as a means of overcoming practical difficulties in converting livestock manure to biochar. We examined the initiating temperature required to induce self-heating of wet dairy cattle manure under 1.0 MPa pressure and conducted elemental and calorific analyses of the solid products prepared at 200, 250, and 300 °C.

A new approach to stabilize waste biomass for valorization using an oxidative process at 90 °C.

This study aimed to establish a new methodology for upgrading biomass quality using low-temperature (below 100 °C) oxidation to achieve simultaneous drying and decomposition. Sterilized manure (63% wet basis) was heated at 90 °C for 49 days under an oxidative environment. The obtained solid and moisture reduction curves indicated that drying and decomposition proceeded simultaneously.

Enhanced thermoelectric figure of merit in stannite-kuramite solid solutions Cu(2+x)Fe(1-x)SnS(4-y) (x = 0-1) with anisotropy lowering.

In this Article, we elucidate the structural and thermoelectric properties of stannite-kuramite solid solutions, Cu(2+x)Fe(1-x)SnS(4-y) (x = 0-1), with sulfur defects (y) ≤ 0.4. Structural analysis revealed that anisotropy decreases and Cu/Sn disorder increases with an increase in x.