Publications by authors named "Tabrez A Khan"

This study evaluated the healthiness of meat products (n = 62) and their plant-based (PB) counterparts (n = 62) available in the UK market. Back-of-pack (BoP) and front-of-pack (FoP) nutrition label information, nutrition and health claims, and nutrient profiling model scores were compared. BoP labels revealed that meat products had higher protein, fat, and saturated fat content ( = 0.

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This research focuses on the modification of pectin through an amination reaction, followed by the development of a novel iminodiacetic acid-functionalized pectin/montmorillonite hydrogel nanocomposite (IMAP/MMT) using gamma radiation. This composite was investigated as an adsorbent for 4-nitrophenol removal from aqueous solutions. Central composite design was utilized for numerical optimization, identifying the maximum adsorption capacity under optimal conditions [0.

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The increasing usage of phosphate fertilizers for agricultural purposes has led to an augmented level of phosphorus in watercourses negatively impacting the ecosystems and water quality warranting its amputation from polluted water. This article describes the preparation of a novel natural deep eutectic solvent (NADES) functionalized-celite/polyethylene glycol hydrogel nanocomposite (NADES-Cel/PEG HNC) for adsorptive phosphate removal from water. The XRD, FTIR, SEM coupled with EDX spectroscopy, TEM, BET analysis, and pH measurement were used to characterise the prepared material.

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The purpose of the study was to fabricate sustainable and cost-effective material for the thorough cleansing of polluted water. In this context, an economical, phytogenic and multifunctional Origanum vulgare plant-based nanocomposite material, MnFeO/OV, was prepared via one-pot synthetic technique. The synthesized nanocomposite with a band gap of 2.

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In recent times, biopolymer-metal oxide nanocomposites have gained prominent importance in the attenuation of environmental toxicants from aqueous phase. But lanthanide oxide-based biopolymer nanocomposites have scantly been evaluated for their adsorption potential. A novel guar gum-polyacrylamide/erbium oxide nanocomposite (GG-PAAm/ErO NC) adsorbent was synthesized by copolymerization of guar gum (GG) and acrylamide (AAm) utilizing N-N'-methylenebisacrylamide as a crosslinker and ErO as a reinforcing agent.

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In the present investigation, a novel, green, and economical dual-functionalized pullulan/kaolin hydrogel nanocomposite (-PKHN) was fabricated and subsequently applied for the liquid-phase decontamination of paracetamol (PCT), a pharmaceutical pollutant. Pullulan and kaolin were functionalized with l-asparagine and gallic acid, respectively. The physicochemical facets of the functionalized pullulan/kaolin hydrogel nanocomposite and its interactive behavior with PCT were elucidated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX), and elemental mapping.

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The adsorption of acridine orange and Cr ion onto plaster of paris reinforced glutamic acid-grafted-polyacrylamide hydrogel nanocomposite modified with riboflavin, Glu-g-PAM/POP/Rb HNC was studied. The Glu-g-PAM/POP/Rb HNC was physico-chemically characterized by Fourier transform infrared spectroscopy, X-ray diffraction analysis, scanning electron microscopy coupled with energy dispersive X-ray spectroscopy, transmission electron microscopy and Brunauer-Emmett-Teller analysis. The specific surface area, pore volume and pore diameter were 15.

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Printing and dyeing wastewater (PDW) has characteristics of large amount of water, elevated content of residual dyes, poor biodegradability, high alkalinity and large change of water quality, making its treatment difficult. Development of efficient and economic PDW treatment technology has gained considerable interest in the field of environmental protection. Use of plant biomass carbon (PBC) for the adsorption of dyes is a feasible and economical technology.

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Herein, a magnetic biochar adsorbent based on discarded peels impregnated with precursor FeCl6HO was fabricated and probed as a low-cost adsorbent for toxic cationic dye methylene blue (MB). The textural characterization of magnetic biochar (PMBC) obtained from BET analysis exhibited its mesoporous nature with S of 133.960 m/g.

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Herein, a functionalized green hydrogel nanocomposite based on carboxymethylated gum tragacanth and nanobentonite (GTBCH) was designed via free-radical polymerization approach for the elimination of Aspartame (AS) from wastewater. The GTBCH fabrication was validated by Fourier Transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Transmission electron microscopy (TEM), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX) techniques. Central composite design (CCD) was efficaciously applied to determine the quadratic polynomial approach for predicting the adsorption capacity (q) of AS.

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Herein, kaolin (K) was amended by a novel gemini surfactant to attain nano-kaolin (nK), which was subsequently employed as a cross-linker in the preparation of itaconic acid/kaolin hydrogel nanocomposite (IA/nK) via free radical polymerization route employing the sonochemical technique, which has been used for the first time to extract metformin (MF) from water solution. The aspects which affect sorption behavior of IA/nK on metformin (MF) were systematically investigated via batch experiments, in harmony with effect of sorbent dosage, contact time, pH, MF concentration, equilibrium curves, kinetic behavior, and thermodynamic parameters. BET studies of IA/nK exhibited S of 106.

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Herein, a simplistic redox polymerization strategy was utilized for the fabrication of a poly(methacrylic acid)/montmorillonite hydrogel nanocomposite (PMA/nMMT) and probed as a sorbent for sequestration of two pharmaceutical contaminants, viz., amoxicillin (AMX) and diclofenac (DF), from wastewater. The synthesized hydrogel nanocomposite was characterized by the Fourier transform infrared, X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy-energy dispersive X-ray spectroscopy, and transmission electron microscopy techniques to analyze structural characteristics and sorption interactions.

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Clay-hydrogel nanocomposites are suitable material for mitigating the pollution/environmental impact because of their high adsorption capacity. In this study, the synthesis of polyacrylamide/bentonite hydrogel nanocomposite was assisted by ultrasound through successful incorporation of nanobentonite as filler and cross-linker into polyacrylamide framework. The adsorbent was characterized by FTIR, XRD, BET, SEM-EDX, and TEM in order to observe structural changes and sorption interactions.

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The present study explores the reducing and capping potentials of aqueous Raphanus sativus root extract for the synthesis of silver nanomaterials for the first time in the absence and presence of two stabilizers, namely, water-soluble starch and cetyltrimethylammonium bromide (CTAB). The surface properties of silver nanoparticles (AgNPs) were determined by dynamic light scattering (DLS), transmission electron microscopy (TEM), energy dispersion X-ray spectroscopy (EDX), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared (FT-IR) techniques. The mean size of AgNPs, ranging from 3.

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In this paper we report the UV-visible and transmission electron microscopy (TEM) evidence to the formation of stable yellow-orange colored complex, which is attributed to the formation of ion-pair between sub-aggregates of cetyltrimethylammonium bromide (CTAB) and gold at room temperature. The position of wavelength maxima (λmax) and shape of the spectra strongly depends on the reaction conditions, i.e.

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Bagasse fly ash (BFA, a sugar industrial waste) was used as low-cost adsorbent for the uptake of arsenate and arsenite species from water. The optimum conditions for the removal of both species of arsenic were as follows: pH 7.0, concentration 50.

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Arsenic contamination of groundwater is a major threat to human beings globally. Among various methods available for arsenic removal, adsorption is fast, inexpensive, selective, accurate, reproducible and eco-friendly in nature. The present paper describes removal of arsenate from water on zirconium oxide-coated sand (novel adsorbent).

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Water pollution due to organic contaminants is a serious issue because of acute toxicities and carcinogenic nature of the pollutants. Among various water treatment methods, adsorption is supposed as the best one due to its inexpensiveness, universal nature and ease of operation. Many waste materials used include fruit wastes, coconut shell, scrap tyres, bark and other tannin-rich materials, sawdust and other wood type materials, rice husk, petroleum wastes, fertilizer wastes, fly ash, sugar industry wastes blast furnace slag, chitosan and seafood processing wastes, seaweed and algae, peat moss, clays, red mud, zeolites, sediment and soil, ore minerals etc.

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Polysaccharide CSPs are recognized widely in chiral chromatography but the introduction of immobilized phases (Chiralpak IA, Chiralpak IB and Chiralpak IC columns) is a remarkable achievement. The immobilized CSPs can be used with organic, normal and reversed phase modes; even with prohibited solvents too (tetrahydrofuran, chlorofom, dichloromethane, acetone, 1,4-dioxane, ethylacetate, and certain other ethers). Their susceptibilities to work with a wide range of solvents have increased the range of applications including chiral recognition mechanisms.

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Purpose: Arsenic, a toxic metalloid in drinking water, has become a major threat for human beings and other organisms. In the present work, attempts have been made to remove arsenate from the synthetic as well as natural water of Ballia district, India by electrocoagulation method. Efforts have also been made to optimize the various parameters such as initial arsenate concentration, pH, applied voltage, processing time, and working temperature.

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