In this study, the results of a comprehensive assessment of the variability in the occurrence of ten perfluorinated compounds (PFAS) in fish tissues originating from 2014 to 2019 from six fisheries in the Baltic Sea are presented. A total of 360 fish samples of three species (perch, herring and flatfish) were analysed. For the determination of PFAS, both linear and branched stereoisomers, LC-ESI-MS/MS technique preceded by simultaneous SPE isolation was validated and applied.
View Article and Find Full Text PDFJ Environ Radioact
September 2024
Certified reference material (CRM) for natural (K,Pb,Po,Ra,Ra,Th,Th,Th,U,U, andU) and anthropogenic (Cs,Pu, andAm) radionuclides in marine sediment from the Baltic Sea (IAEA-465) has been developed. Information values are given for Pu,Pu andPu. Altogether 27 laboratories participated in this exercise.
View Article and Find Full Text PDFA remarkable feature of the brain is its sexual dimorphism. Sexual dimorphism in brain structure and function is associated with clinical implications documented previously in healthy individuals but also in those who suffer from various brain disorders. Sex-based differences concerning some features such as the risk, prevalence, age of onset, and symptomatology have been confirmed in a range of neurological and neuropsychiatric diseases.
View Article and Find Full Text PDFThe research aimed to determine the scale of the potential contamination of the southern Baltic by substances from dumped chemical weapons, in the context of applying a strategy for detecting the potential releases of toxic materials. The research included the analysis of total arsenic in sediments, macrophytobenthos, fish, and yperite with derivatives and arsenoorganic compounds in sediments and as an integral part of the warning system the threshold values for arsenic in these matrices were set. Arsenic concentrations in sediments ranged from 11 to 18 mg kg with an increase to 30 mg kg in layers dated to 1940-1960, what was accompanied by the detection of triphenylarsine (600 mg kg).
View Article and Find Full Text PDFFor many years Antarctic ecosystems have been considered pristine, however recent studies, including our results, contradict this assumption. Our comprehensive study on the activity of anthropogenic radioisotopes (Cs and Sr) in the most common species of green algae, bryophytes, lichens, and vascular plants, as well as soil and guano samples collected over a large area on King George Island (South Shetland Archipelago) in the austral summer 2018/2019 clearly indicate the importance of large-scale transport in shaping the level of pollution in areas very distant from potential sources of contamination. Additionally, radioisotope pollution can be measured even after a very long period (>60 years) since their occurrence.
View Article and Find Full Text PDF