Durable Pulse-Electrodeposited Ni-Fe-S Nanosheets Supported on a Ni-S Three Dimensional Pattern as Robust Bifunctional Electrocatalysts for Hydrogen Evolution and Urea Oxidation Reactions.

This study aims to establish easy-to-fabricate and novel structures for the synthesis of highly active and enduring electrocatalysts for the hydrogen evolution reaction (HER) and urea oxidation reaction (UOR). Gradient electrodeposition and four different time regimes were utilized to synthesize Ni-S 3D patterns with the optimization of electrodeposition time. Pulse electrodeposition was employed for the synthesis of Ni-Fe-S nanosheets at three different frequencies and duty cycles to optimize the pulse electrodeposition parameters.

Sustainable development of an effective anti-corrosion film over the St12-steel surface against seawater attacks using Ce(III) ions/tri-sodium phosphate anions.

One application of organic compounds is to utilize them as corrosion inhibitors in acidic environments to diminish steel corrosion. These inhibitors do not show very good inhibition properties in saline (NaCl) environments. There have been many studies on boosting these inhibitors' performance in such environments (especially Cl containing media).

Optimization of nickel selenide for hydrogen and oxygen evolution reactions by response surface methodology.

In this study, the electrocatalytic activity of Ni-Se electrode synthesized on nickel foam by pulse electrodeposition was optimized through the design of experiments (DOE) approach using the response surface methodology (RSM) for both hydrogen and oxygen evolution reactions. The frequency (f), duty cycle (dc), current density (i), and electrodeposition time (sum of ts) were chosen as the parameters of the pulse electrodeposition method. The analyses of variance (ANOVA) were performed on the responses of the designed experiments that included the required overpotential at the current density of 10 mA/cm for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) (η and η), active surface area (R) and intrinsic electrocatalytic activity (i/R).

Epoxy coating anti-corrosion properties enhancement via the steel surface treatment by nanostructured samarium oxide-poly-dopamine film.

Nowadays, the rare earth element-based conversion coatings (REE-based CCs) are a potential eco-friendly alternative for hazardous and carcinogenic Cr-based CCs. These coatings have morphological defects that impair their performance; therefore, they need to be surface modified. In this study, for the first time, the steel surface was coated with an eco-friendly Sm-based CC and then post-modified by poly-dopamine based biopolymer.

Development of a nanostructured film based on samarium (III)/polydopamine on the steel surface with superior anti-corrosion and water-repellency properties.

Hypothesis: The application of various hydrophobic/superhydrophobic coatings on the surface of metals has become the hot topic of the recent studies. The corrosion protection effectiveness and environmental issues are two important factors that should be taken into consideration when developing advanced surface coatings. Recently, the rare-earth elements (i.