Orientational order induced by a polymer network in the isotropic phase of liquid crystal.

We studied the paranematic ordering induced by a polymer network in the isotropic phase of a liquid crystal (LC) that occurs in polymer-stabilized cells with bend configuration of the LC director (π cells) fabricated via photopolymerization of photoreactive monomer RM 82 added in small concentrations (3-5 wt %) to a nematic LC [4-cyano-4'-pentylbiphenyl (5CB)] when low voltage was applied across the cell. The polymer network formed in the nematic phase of the LC consists of fine fibrils that are aligned along the LC director and thus mirror the bend deformation of the LC at the time of polymerization. When heated to temperatures above the nematic-to-isotropic (N-I) phase transition such highly ordered polymer network anchors LC molecules providing ordering of the LC around the fibrils which results in unusually high optical retardation of the cell, R_{cell}.

Comparative study of the anchoring strength of reactive mesogens and industrial polyimides used for the alignment of liquid crystals.

We measured the Rapini-Papoular polar anchoring strength coefficient W for 4^{'}-pentyl-4-cyanobiphenyl (5CB) on alignment layers formed by the reactive mesogen photopolymers RM 257, RM 82, and RM 84 [4,4^{'}-bis(acryloyl)biphenyl] (by Merck). These materials are commonly used for the photostabilization of the liquid crystal (LC) director in the bulk as well as at the surface of the LC layer via the formation of a loose polymer network that captures the director orientation. We developed a method of fabrication of alignment layers from these polymers, and estimated W from the measurements of the optical retardation as a function of applied voltage in uniformly aligned cells.

Switchable broadband achromatic half-wave plate with nematic liquid crystals.

We describe a broadband achromatic half-wave retarder for normally incident light of arbitrary polarization. The device consists of a stack of one nematic liquid-crystal cell with uniform alignment sandwiched between two twisted nematic layers that have identical twist angles (135 degrees) but different orientations of their surface alignment. As a specific application, for light with linear polarization at 45 degrees to the optic axis of the homogeneous cell the stack functions efficiently as an optical switch.

Measurement and modeling of optical performance of wire grids and liquid-crystal displays utilizing grid polarizers.

We studied the optical performance of a reflective wire-grid polarizer designed for visible light. The polarizer reflects E polarization and transmits H polarization with low losses. The studies of transmission and reflectivity of nonpolarized and polarized light from single grids and stacked grids show that the optical performance of wire-grid polarizers can be adequately described by representing the polarizer as an effective uniaxial medium with anisotropic absorption.