The chemical flexibility of the tetragonal tungsten bronze (TTB) structure offers a large potential for compositional engineering. Cation size and vacancy concentration are known to affect its structure, cation disorder, and functional properties. However, the compositional complexity also makes the TTB structure challenging to understand.
View Article and Find Full Text PDFAnodic TiO nanotube arrays decorated with Ni, Cu, and NiCu alloy thin films were investigated for the first time for the photocatalytic degradation of paracetamol in water solution under UV irradiation. Metallic co-catalysts were deposited on TiO nanotubes using magnetron sputtering. The influence of the metal layer composition and thickness on the photocatalytic activity was systematically studied.
View Article and Find Full Text PDFWien Klin Wochenschr
August 2024
Myalgic encephalomyelitis/chronic fatigue syndrome (ME/CFS) is a severe, chronic multisystemic disease which, depending on its severity, can lead to considerable physical and cognitive impairment, loss of ability to work and the need for nursing care including artificial nutrition and, in very severe cases, even death.The aim of this D-A-CH (Germany, Austria, Switzerland) consensus statement is 1) to summarize the current state of knowledge on ME/CFS, 2) to highlight the Canadian Consensus Criteria (CCC) as clinical criteria for diagnostics with a focus on the leading symptom post-exertional malaise (PEM) and 3) to provide an overview of current options and possible future developments, particularly with regard to diagnostics and therapy. The D-A-CH consensus statement is intended to support physicians, therapists and valuer in diagnosing patients with suspected ME/CFS by means of adequate anamnesis and clinical-physical examinations as well as the recommended clinical CCC, using the questionnaires and other examination methods presented.
View Article and Find Full Text PDFZeiformes (dories, tinselfishes, and oreos) are primarily benthopelagic acanthomorph fishes, distributed between 50 and 1000 m depth on continental slopes and on flanks of oceanic islands and seamounts. Among the interesting morphological adaptations of zeiform fishes are their unique and highly protrusible jaws involving premaxillae with long ascending processes and a four-bar linkage, including mobile palatines that pivot on their posterior articulation. This adaptation for increased jaw protrusion has enabled zeiform fishes to capture elusive prey more efficiently and is arguably a major factor in their morphological diversity and evolutionary success.
View Article and Find Full Text PDFThe second largest family of oxide ferroelectrics, after perovskites, are the tetragonal tungsten bronzes (TTB) with the general formula A2A1CB1B2O. Cation disorder in TTBs is known to occur if the size difference between cations is small, but the impact of cation disorder on structure and properties has not yet been extensively addressed. In this study we investigate the effect of the size of the M cation, including cation disorder, on the crystal structure and dielectric properties in the two series BaMNbO (BMN, A = Na, K and Rb) and BaMNbTiO (BMNT, M = Ca, Sr).
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