Publications by authors named "T K Dickens"

Structural health monitoring (SHM) systems are critical in ensuring the safety of space exploration, as spacecraft and structures can experience detrimental stresses and strains. By deploying conventional strain gauges, SHM systems can promptly detect and assess localized strain behaviors in structures; however, these strain gauges are limited by low sensitivity (gauge factor, GF ∼ 2). This study introduces an approach to printing strain gauges with high sensitivity, while also considering stretchability and long-term durability.

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The closed-shell Hückel-London-Pople-McWeeny formalism for ring currents is extended to Aufbau configurations with open shells calculated as configurational averages. The method is applied to the non-Kekulean benzenoid known as the Clar goblet, recently synthesized on the Au(111) surface. Multiplicity of the ground state is a complication: for the Clar goblet, Hund's rule of maximum multiplicity implies a triplet whereas Ovchinnikov's rule implies a singlet.

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Halide perovskites have exhibited great research impact for developing innovative materials with novel properties. Here, we report the synthesis of different caesium lead bromide perovskites using different (Cs/Pb) molar ratios and fabrication of their corresponding perovskite/polyvinylidene fluoride (PVDF) composites, as well as study of their structural and UV-photodetection properties. Spin-coated perovskite/PVDF composite thin films revealed strong oriented XRD diffraction peaks along the -axis direction (00l) with homogeneously distributed perovskite microcrystals in the polymer matrix.

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Bismuth-based perovskites are promising candidates for highly stable halide perovskites with low toxicity. Here, we report the synthesis of a series of bismuth iodide-based perovskites with different primary, secondary, and tertiary ammonium cations and study their structural, thermal, and optical properties, and the likelihood of photodetection. Interestingly, the variation of A-site organic ammonium cations, with different interlayer spacings between adjacent bismuth iodide monolayers, has exotic effects on the diffraction patterns and morphological structures of the perovskite crystals.

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The recent trends of vitrimer studies enhance the thermoset material with superior properties, therefore, it is particularly important to address the critical scientific inquiries in this area using their research metrics. The reported vitrimer systems have been highly required for future real-time applications; however, the inquisitiveness of material exchange mechanisms extends the research studies further. Significantly, more scientific information's are required to achieve the evident prospective outcomes these materials.

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