Pauli Shielding and Breakdown of Spin Statistics in Multielectron Multi-Open-Shell Dynamical Atomic Systems.

We report on C^{3+}(1s2ℓ2ℓ^{'} ^{2S+1}L)-resolved cross sections of electron capture in collisions of swift C^{4+}(1s2s ^{3}S) ions with helium and hydrogen. The study focuses on the formation of doubly excited triply open-shell C^{3+}(1s2s2p) ^{4}P and ^{2}P_{±} states with emphasis on the ratio R of their cross sections as a measure of spin statistics. Using zero-degree Auger projectile spectroscopy and a three-electron close-coupling semiclassical approach, we resolve a long-standing puzzle and controversy on the value of R and on the effect of cascades, to clarify the underlying physics.

Determination of the solid angle and response function of a hemispherical spectrograph with injection lens for Auger electrons emitted from long lived projectile states.

We present SIMION 8.1 Monte Carlo type simulations of the response function and detection solid angle for long lived Auger states (lifetime τ ∼ 10(-9) - 10(-5) s) recorded by a hemispherical spectrograph with injection lens and position sensitive detector used for high resolution Auger spectroscopy of ion beams. Also included in these simulations for the first time are kinematic effects particular to Auger emission from fast moving projectile ions such as line broadening and solid angle limitations allowing for a more accurate and realistic line shape modeling.

Electron rearrangement dynamics in dissociating I(2)^(n+) molecules accessed by extreme ultraviolet pump-probe experiments.

The charge rearrangement in dissociating I_{2}^{n+} molecules is measured as a function of the internuclear distance R using extreme ultraviolet pulses delivered by the free-electron laser in Hamburg. Within an extreme ultraviolet pump-probe scheme, the first pulse initiates dissociation by multiply ionizing I_{2}, and the delayed probe pulse further ionizes one of the two fragments at a given time, thus triggering charge rearrangement at a well-defined R. The electron transfer between the fragments is monitored by analyzing the delay-dependent ion kinetic energies and charge states.

Experimental energy resolution of a paracentric hemispherical deflector analyzer for different entry positions and bias.

A specially designed hemispherical deflector analyzer (HDA) with 5-element input lens having a movable entry position R0 suitable for electron energy analysis in atomic collisions was constructed and tested. The energy resolution of the HDA was experimentally determined for three different entry positions R0 = 84, 100, 112 mm as a function of the nominal entry potential V(R0) under pre-retardation conditions. The resolution for the (conventional) entry at the mean radius R0 = 100 mm was found to be a factor of 1.

Controlling two-electron threshold dynamics in double photoionization of lithium by initial-state preparation.

Double photoionization (DPI) and ionization-excitation (IE) of Li(2s) and Li(2p), state-prepared and aligned in a magneto-optical trap, were explored in a reaction microscope at the free-electron laser in Hamburg (FLASH). From 6 to 12 eV above threshold (homega = 85, 91 eV), total as well as differential DPI cross sections were observed to critically depend on the initial state and, in particular, on the alignment of the 2p orbital with respect to the VUV-light polarization, whereas no effect is seen for IE. The alignment sensitivity is traced back to dynamical electron correlation at threshold.