Publications by authors named "T E Fritz"

Ultraflat metal foils are essential for semiconductor nanoelectronics applications and nanomaterial epitaxial growth. Numerous efforts have been devoted to metal surface engineering studies in the past decades. However, various challenges persist, including size limitations, polishing non-uniformities, and undesired contaminants.

View Article and Find Full Text PDF

Weakly interacting systems such as organic molecules on monolayers of hexagonal boron nitride (h-BN) offer the possibility of single integer charge transfer leading to the formation of organic ions. Such open-shell systems exhibit unique optical and electronic properties which differ from their neutral counterparts. In this study, we used a joint experimental and theoretical approach to investigate the charge transfer of perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) molecules on h-BN/Ni(111) by using differential reflectance spectroscopy (DRS), scanning tunneling spectroscopy (STS), and photoelectron orbital tomography (POT) measurements in combination with density functional theory (DFT) calculations.

View Article and Find Full Text PDF

Attention-deficit/hyperactivity disorder (ADHD) is a neurodevelopmental condition characterized by patterns of inattention and impulsivity, which lead to difficulties maintaining concentration and motivation while completing academic tasks. University settings, characterized by a high student-to-staff ratio, make treatments relying on human monitoring challenging. One potential replacement is Virtual Reality (VR) technology, which has shown potential to enhance learning outcomes and promote flow experience.

View Article and Find Full Text PDF

The π-conjugation of organic molecules can be strongly influenced when functional groups are added to a molecule, for example when pentacene is converted into pentacene-5,7,12,14-tetrone (P4O) by substitution of four H-atoms with four O-atoms, leading to four CO double bonds. In fact, although free P4O resembles the parent hydrocarbon pentacene structurally at a first glance, its electronic properties differ drastically and can be more accurately described by three benzene units connected four carbonyl groups. If P4O is deposited onto Cu(111), the electronic interaction across the interface has previously been reported to fully restore the π-conjugation through a weakening of the CO double bonds and a redistribution of electrons, both of which have been explained with the model of surface-induced aromatic stabilization.

View Article and Find Full Text PDF
Article Synopsis
  • Antiviral drugs targeting SARS-CoV-2, particularly the main protease (M), are crucial for preventing future COVID outbreaks.
  • The study reveals that M undergoes redox regulation, switching between an active dimer and a dormant monomer, affecting its function through modifications of specific cysteine residues.
  • The findings also identify potential druggable sites in the form of conserved redox switches, which could be found in main proteases of other coronaviruses like MERS-CoV and SARS-CoV.
View Article and Find Full Text PDF