Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application.

There is a mounting demand for nonlinear optical materials with superior optical limiting performance which has a noticeable impact on protecting the delicate optical components from laser-induced damage. Transition metal molybdates have garnered attention in the nonlinear optics field due to their outstanding optical and luminescent properties, which give rise to widespread applications in next-generation optoelectronics devices. The structural confirmation of the as prepared silver molybdate nanoparticles were made by XRD and Raman spectroscopy analysis.

Experimental and Computational studies on Intramolecular charge transfer, Terahertz and Two photon absorption of 3-[(4-Nitrophenyl Azo)]-9H-Carbazole-9-Ethanol (NPACE) from their Vibrational spectra for Optical limiting and NLO applications.

Non-linear optical (NLO) features of 3-[(4-Nitrophenyl Azo)]-9H-Carbazole-9-Ethanol (NPACE) chromophore were investigated by FT-IR, FT-Raman, and UV-visible spectra aided by Density Functional Theory (DFT) using the B3LYP/6-311++G(d,p) basis set of Gaussian 16 W package. It is observed from the DFT calculation that the slight increase in the endocyclic angle of C -C -C and the reduction in exocyclic angle of N -N -C and C -C -N ascertained by experimental XRD values indicating the intramolecular charge-transfer interaction between the carbazole and nitrophenyl group through the diazo bridge. The vibrational contribution to the linear electro-optic effect is 15% of the total hyperpolarizability being calculated at B3LYP/6-311++G (d, p) for the NPACE molecule.

Influence of yttrium doping on the nonlinear optical limiting properties of cadmium molybdate nanostructures.

The emerging demand for the production of nonlinear optical materials with high optical limiting performance has an apparent impact in the field of nonlinear optics owing to their wide application in photonic devices. In this regard, transition metal molybdates have received attention owing to their remarkable optical and luminescence characteristics, leading to their extensive use in next generation optoelectronics devices. Herein, we report the nonlinear optical response of yttrium (Y) doped cadmium molybdate (CdMoO) nanostructures synthesized a co-precipitation technique.

Bis(benzo-15-crown-5-κ )barium tetra-kis-(iso-thio-cyanato-κ)cobaltate(II).

The title compound, [Ba(CHO)][Co(NCS)], is formed by discrete anions and cations. The molecular packing is controlled by weak C-H⋯π inter-actions.

Tunable photovoltaic performance of preferentially oriented rutile TiO nanorod photoanode based dye sensitized solar cells with quasi-state electrolyte.

Photoanodes made of highly oriented TiO nanorod (NR) arrays with different aspect ratios were synthesized via a one-step hydrothermal technique. Preferentially oriented single crystalline rutile TiO was confirmed by the single peak in an XRD pattern (2θ = 63°, (0 0 2)). FESEM images evidenced the growth of an array of NRss having different geometries with respect to reaction time and solution refreshment rate.