Anodic Activation of Prussian Blue Analog Leads to Highly Active Cobalt-doped Nickel (Oxy)hydroxide for Organic Oxidation Reactions.

Water-assisted electrocatalytic oxidation of alcohols into valuable chemicals is a promising strategy to circumvent the sluggish kinetics of water oxidation, while also reducing cell voltage and improving energy efficiency. Recently, transition metal (TM)-based catalysts have been investigated for anodic alcohol oxidation, but success has been limited due to competition from the oxygen evolution reaction (OER) within the working regime. In this study, NiCo-based Prussian blue analog (PBA) was electrochemically activated at the anodic potential to produce a Co-Ni(O)OH active catalyst with a nanosheet-like architecture.

Revolutionizing Limb Preservation: A Case Report on Recurrent Fungating Giant Cell Tumor with Encased Radial Artery in the Distal Radius.

Introduction: Giant cell tumor (GCT) of the bone, although benign, poses significant challenges due to its locally aggressive nature and high recurrence rates post-surgical intervention. Among skeletal GCTs, those affecting the distal radius present unique difficulties, especially when fungating masses encase vital structures such as blood vessels.

Case Report: We present a case of a 28-year-old male with a recurring GCT of the distal radius, where limb-preserving surgery was successfully performed despite encasement of the radial artery.

Ni(II)-Dithiocarbamate and -diphosphine coordination complexes as pre-catalysts for electrochemical OER activity.

Electrochemical water oxidation holds immense potential for sustainable energy generation, splitting water into clean-burning hydrogen and life-giving oxygen. However, a key roadblock lies in the sluggish nature of the oxygen evolution reaction (OER). Finding stable, cost-effective, and environmentally friendly catalysts with high OER efficiency is crucial to unlock this technology's full potential.

Mirror hand and its management: a case report.

Background: Mirror hand is a rare congenital anomaly. Most of these cases are sporadic and associated with defective sonic hedgehog during embryogenesis. In this report, we present the case of a child with this rare congenital anomaly and its management.

Association of Hyperlipidemia and Hyperglycemia With Cognitive Function in Type 2 Diabetes: A Cross-Sectional Analysis.

Introduction Cognitive impairment is increasingly recognized as a significant health concern, particularly in the early stages of diabetes. The type and severity of cognitive deficits may vary with the duration of diabetes and the effectiveness of glucose management. Complications associated with metabolic syndrome may exacerbate these cognitive declines.