Making the case for an International Decade of Radiocarbon.

Radiocarbon (C) is a critical tool for understanding the global carbon cycle. During the Anthropocene, two new processes influenced C in atmospheric, land and ocean carbon reservoirs. First, C-free carbon derived from fossil fuel burning has diluted C, at rates that have accelerated with time.

Simultaneous Determination of Transuranium Radionuclides for Nuclear Forensics by Compact Accelerator Mass Spectrometry.

Accelerator mass spectrometry (AMS) is one of the most sensitive techniques used to measure the long-lived actinides. This is particularly of interest for determination of ultra-trace transuranium nuclides and their isotopic fingerprints for nuclear forensics. In this work, a new method was developed for simultaneous determination of transuranium nuclides (Np, Pu, Am, and Cm isotopes) by using 300 kV AMS after a sequential chemical separation of each group of actinides.

Tree-rings reveal two strong solar proton events in 7176 and 5259 BCE.

The Sun sporadically produces eruptive events leading to intense fluxes of solar energetic particles (SEPs) that dramatically disrupt the near-Earth radiation environment. Such events have been directly studied for the last decades but little is known about the occurrence and magnitude of rare, extreme SEP events. Presently, a few events that produced measurable signals in cosmogenic radionuclides such as C, Be and Cl have been found.

Accelerator Mass Spectrometry: Ultra-sensitive Detection Technique of Long-lived Radionuclides.

An introduction is given to accelerator mass spectrometry (AMS) technology, to the fundamental measurement principles, and the physics aspects behind the design constrain of AMS instruments. This article shall give an overview on technical design constraints of AMS instrumentation, general ion optical principles, and nuclide specific problems. The historic development of AMS detection techniques is briefly summarized.

Cosmogenic radionuclides reveal an extreme solar particle storm near a solar minimum 9125 years BP.

During solar storms, the Sun expels large amounts of energetic particles (SEP) that can react with the Earth's atmospheric constituents and produce cosmogenic radionuclides such as C, Be and Cl. Here we present Be and Cl data measured in ice cores from Greenland and Antarctica. The data consistently show one of the largest Be and Cl production peaks detected so far, most likely produced by an extreme SEP event that hit Earth 9125 years BP (before present, i.

Double Trap Interface: A novel gas interface for high throughput analysis of biomedical samples by AMS.

Although Accelerator Mass Spectrometry (AMS) offers unparalleled sensitivity by investigating the fate of C-labeled compounds within the organism, its widespread use in ADME (absorption, distribution, metabolism, excretion) studies is limited. Conventional approaches based on Liquid Scintillation Counting (LSC) are still preferred, in particular because of complexity and costs associated with AMS measurements. Progress made over the last decade towards more compact AMS systems increased the interest in a combustion-based AMS approach allowing the analysis of samples in gaseous form.

Unravelling 5 decades of anthropogenic U discharge from nuclear reprocessing plants.

Marine biogenic materials such as corals, shells, or seaweed have long been recognized as recorders of environmental conditions. Here, the bivalve Cerastoderma edule is used for the first time as a recorder of past seawater contamination with anthropogenic uranium, specifically U. Several studies have employed the authorized radioactive releases, including U, from nuclear reprocessing plants in La Hague, France, into the English Channel, and Sellafield, England, into the Irish Sea, to trace Atlantic waters and to understand recent climate induced circulation changes in the Arctic Ocean.

Dual isotope system analysis of lead white in artworks.

Isotopic studies are gaining much interest in heritage science, as they can provide insight into a material's age and provenance. Radiocarbon (14C) dating affords a time frame for the materials being studied, thus providing a historical context, whereas the specific pattern of lead isotope ratios may be used to set geographical constraints on the source of the original materials. Both methods require invasive sampling from the object, and henceforth limits their respective application.

Radionuclides in surface waters around the damaged Fukushima Daiichi NPP one month after the accident: Evidence of significant tritium release into the environment.

Following the Fukushima nuclear accident (2011), radionuclides mostly of volatile elements (e.g., I, Cs, Te) have been investigated frequently for their presence in the atmosphere, pedosphere, biosphere, and the Pacific Ocean.

Uncovering modern paint forgeries by radiocarbon dating.

Art forgeries have existed since antiquity, but with the recent rapidly expanding commercialization of art, the approach to art authentication has demanded increasingly sophisticated detection schemes. So far, the most conclusive criterion in the field of counterfeit detection is the scientific proof of material anachronisms. The establishment of the earliest possible date of realization of a painting, called the , is based on the comparison of materials present in an artwork with information on their earliest date of discovery or production.

Multiradionuclide evidence for an extreme solar proton event around 2,610 B.P. (∼660 BC).

Recently, it has been confirmed that extreme solar proton events can lead to significantly increased atmospheric production rates of cosmogenic radionuclides. Evidence of such events is recorded in annually resolved natural archives, such as tree rings [carbon-14 (C)] and ice cores [beryllium-10 (Be), chlorine-36 (Cl)]. Here, we show evidence for an extreme solar event around 2,610 years B.

Tree rings reveal globally coherent signature of cosmogenic radiocarbon events in 774 and 993 CE.

Though tree-ring chronologies are annually resolved, their dating has never been independently validated at the global scale. Moreover, it is unknown if atmospheric radiocarbon enrichment events of cosmogenic origin leave spatiotemporally consistent fingerprints. Here we measure the C content in 484 individual tree rings formed in the periods 770-780 and 990-1000 CE.

Evaluation of cAMS for C microtracer ADME studies: opportunities to change the current drug development paradigm.

Aim: Although regulatory guidances require human metabolism information of drug candidates early in the development process, the human mass balance study (or hADME study), is performed relatively late. hADME studies typically involve the administration of a C-radiolabelled drug where biological samples are measured by conventional scintillation counting analysis. Another approach is the administration of therapeutic doses containing a C-microtracer followed by accelerator mass spectrometry (AMS) analysis, enabling hADME studies completion much earlier.

Anthropogenic U in the North Sea - A Closer Look into a Source Region.

In this study we present new seawater data of U and U sampled in the North Sea in 2010. The North Sea has been and is still receiving a considerable input of anthropogenic radionuclides from nuclear reprocessing facilities located in La Hague (France) and Sellafield (Great Britain). It therefore represents an important source region for oceanographic tracer studies using the transient signal of anthropogenic U.

Potential Releases of I, U, and Pu Isotopes from the Fukushima Dai-ichi Nuclear Power Plants to the Ocean from 2013 to 2015.

After the Fukushima Dai-ichi nuclear accident, many efforts were put into the determination of the presence of Cs, Cs, I, and other gamma-emitting radionuclides in the ocean, but minor work was done regarding the monitoring of less volatile radionuclides, pure beta-ray emitters or simply radionuclides with very long half-lives. In this study we document the temporal evolution of I, U, and Pu isotopes (Pu and Pu) in seawater sampled during four different cruises performed 2, 3, and 4 years after the accident, and we compare the results to Cs collected at the same stations and depths. Our results show that concentrations of I are systematically above the nuclear weapon test levels at stations located close to the FDNPP, with a maximum value of 790 × 10 at·kg, that exceeds all previously reported I concentrations in the Pacific Ocean.

Anthropogenic U and I in the Mediterranean Sea: First comprehensive distribution and constrain of their sources.

The first basin-wide distribution of U/U atom ratios and I concentrations is presented for the Mediterranean Sea. During the GEOTRACES GA04S-MedSeA expedition in 2013 seawater was collected from 10 vertical profiles covering the principal sub-basins of the Mediterranean Sea. The main objective was to understand the distributions of U and I in relation to the water masses, and to constrain their sources in this region.

Laser Ablation - Accelerator Mass Spectrometry: An Approach for Rapid Radiocarbon Analyses of Carbonate Archives at High Spatial Resolution.

A new instrumental setup, combining laser ablation (LA) with accelerator mass spectrometry (AMS), has been investigated for the online radiocarbon ((14)C) analysis of carbonate records. Samples were placed in an in-house designed LA-cell, and CO2 gas was produced by ablation using a 193 nm ArF excimer laser. The (14)C/(12)C abundance ratio of the gas was then analyzed by gas ion source AMS.

Iodine-129, Iodine-127 and Cesium-137 in seawater from the North Sea and the Baltic Sea.

In this study, new data are presented for the iodine isotopes (I, I and their isotopic ratios) and Cesium (Cs) in water samples of the North Sea and the Baltic Sea in 2005 and 2009. This study supplements and extends the study of Michel et al. (2012).

Concentrations of iodine isotopes ((129)I and (127)I) and their isotopic ratios in aerosol samples from Northern Germany.

New data about (129)I, (127)I concentrations and their isotopic ratios in aerosol samples from the trace survey station of the Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig, Northern Germany, are presented and discussed in this paper. The investigated samples were collected on a weekly basis during the years 2011 to 2013. Iodine was extracted from aerosol filters using a strong basic solution and was separated from the matrix elements with chloroform and was analysed by accelerator mass spectrometry (AMS) for (129)I and by inductively coupled plasma mass spectrometry (ICP-MS) for (127)I.

Determination of Atto- to Femtogram Levels of Americium and Curium Isotopes in Large-Volume Urine Samples by Compact Accelerator Mass Spectrometry.

Ultralow level analysis of actinides in urine samples may be required for dose assessment in the event of internal exposures to these radionuclides at nuclear facilities and nuclear power plants. A new bioassay method for analysis of sub-femtogram levels of Am and Cm in large-volume urine samples was developed. Americium and curium were co-precipitated with hydrous titanium oxide from the urine matrix and purified by column chromatography separation.

Multiradionuclide evidence for the solar origin of the cosmic-ray events of ᴀᴅ 774/5 and 993/4.

The origin of two large peaks in the atmospheric radiocarbon ((14)C) concentration at AD 774/5 and 993/4 is still debated. There is consensus, however, that these features can only be explained by an increase in the atmospheric (14)C production rate due to an extraterrestrial event. Here we provide evidence that these peaks were most likely produced by extreme solar events, based on several new annually resolved (10)Be measurements from both Arctic and Antarctic ice cores.

Post-Accident Sporadic Releases of Airborne Radionuclides from the Fukushima Daiichi Nuclear Power Plant Site.

The Fukushima nuclear accident (March 11, 2011) caused the widespread contamination of Japan by direct deposition of airborne radionuclides. Analysis of weekly air filters has revealed sporadic releases of radionuclides long after the Fukushima Daiichi reactors were stabilized. One major discharge was observed in August 2013 in monitoring stations north of the Fukushima Daiichi nuclear power plant (FDNPP).

Oral Vitamin D Supplements Increase Serum 25-Hydroxyvitamin D in Postmenopausal Women and Reduce Bone Calcium Flux Measured by 41Ca Skeletal Labeling.

Background: Ensuring adequate vitamin D status in older adults may reduce the risk of osteoporosis. The serum 25-hydroxyvitamin D [25(OH)D] concentration is the recommended biomarker of vitamin D status, but the optimal serum 25(OH)D concentration for bone health in postmenopausal women remains unclear.

Objective: The aim of this study was to apply the highly sensitive (41)Ca skeletal labeling technique and the measurement of urinary (41)Ca:(40)Ca ratios to determine the serum 25(OH)D concentration that has greatest benefit on bone calcium flux in postmenopausal women.