Exact distributions of threshold crossing times of proteins under post-transcriptional regulation by small RNAs.

The timings of several cellular events like cell lysis, cell division, or pore formation in endosomes are regulated by the time taken for the relevant proteins to cross a threshold in number or concentration. Since protein synthesis is stochastic, the threshold crossing time is a first passage problem. The exact distributions of these first passage processes have been obtained recently for unregulated and autoregulated genes.

Optimizing Work Extraction in the Presence of an Entropic Potential: An Entropic Stochastic Resonance.

We study the nontrivial thermodynamic responses of an overdamped Brownian system driven by an unbiased driving force when the particle is confined inside a bilobal irregular structure. The spatial irregularity of the confinement results in an effective entropic bistable potential along the direction of transport. We calculate the thermodynamic response functions in terms of the averaged work done and the absorbed heat over a cycle of driving.

Geometric Brownian information engine: Essentials for the best performance.

We investigate a geometric Brownian information engine (GBIE) in the presence of an error-free feedback controller that transforms the information gathered on the state of Brownian particles entrapped in monolobal geometric confinement into extractable work. Outcomes of the information engine depend on the reference measurement distance x_{m}, the feedback site x_{f}, and the transverse force G. We determine the benchmarks for utilizing the available information in an output work and the optimum operating requisites for best achievable work.

Geometric Brownian information engine: Upper bound of the achievable work under feedback control.

We design a geometric Brownian information engine by considering overdamped Brownian particles inside a two-dimensional monolobal confinement with irregular width along the transport direction. Under such detention, particles experience an effective entropic potential which has a logarithmic form. We employ a feedback control protocol as an outcome of error-free position measurement.

Structural, Electronic, and Spectral Properties of Metal Dimethylglyoximato [M(DMG); M = Ni, Cu] Complexes: A Comparative Theoretical Study.

Dimethylglyoxime (DMG) usually forms thermodynamically stable chelating complexes with selective divalent transition-metal ions. Electronic and spectral properties of metal-DMG complexes are highly dependent on the nature of metal ions. Using range-separated hybrid functional augmented with dispersion corrections within density functional theory (DFT) and time-dependent DFT, we present a detailed and comprehensive study on structural, electronic, and spectral (both IR and UV-vis) properties of M(DMG) [M = Ni, Cu] complexes.