Modification of Sugar Cane Bagasse with CTAB and ZnO for Methyl Orange and Methylene Blue Removal.

Sugar cane bagasse (SB) was modified with cetyltrimethylammonium bromide (CTAB), followed by impregnation with zinc oxide (ZnO) to create a synergistic adsorption and photocatalytic system for methyl orange (MO) and methylene blue (MB) removal. The presence of CTAB and ZnO was confirmed by X-ray diffraction, Fourier transform infrared, and energy dispersive X-ray (for Zn and O). Modification of SB with CTAB (CSB) generated more positive sites on the surface of SB, which enhanced MO removal compared with that of pristine SB.

Spectroscopic Evidence of Localized Small Polarons in Low-Dimensional Ionic Liquid Lead-Free Hybrid Perovskites.

Rational design is an important approach to consider in the development of low-dimensional hybrid organic-inorganic perovskites (HOIPs). In this study, 1-butyl-1-methyl pyrrolidinium (BMP), 1-(3-aminopropyl)imidazole (API), and 1-butyl-3-methyl imidazolium (BMI) serve as prototypical ionic liquid components in bismuth-based HOIPs. Element-sensitive X-ray absorption spectroscopy measurements of BMPBiBr and APIBiBr reveal distinct resonant excitation profiles across the N K-edges, where contrasting peak shifts are observed.

Direct synthesis of Fe-aluminosilicates from red mud for catalytic deoxygenation of waste cooking oil.

Conversion of red mud (RM) that contains a high level of silica, alumina and iron minerals into heterogenous catalysts, offers a route for the utilization of abundant toxic by-products of bauxite refining. In this study, the conversion of red mud into mesoporous Fe-aluminosilicate produced selective catalysts for the deoxygenation of waste cooking oil to green diesel hydrocarbons. Direct conversion of red mud in the presence cetyltrimethylammonium bromide into Fe-aluminosilicate (RM-CTA) produced a highly mesoporous structure with oligomeric FeO clusters within the pores.

Culturable hydrocarbonoclastic marine bacterial isolates from Indonesian seawater in the Lombok Strait and Indian Ocean.

Purpose: The study aims to isolate the culturable marine bacteria and to assess their potential as the bioremediation agent for petroleum hydrocarbons contamination in marine environment.

Methods: Bacteria isolates were obtained by repetitive streaks to obtain purified bacteria on Zobell marine agar plates before further analysis and culture through direct visualization on agar plates. Identification were conducted using 16S rDNA sequence which are compared using NCBI BLAST and, combined with phenotypic and phylogenetic data.

Beach macro-litter monitoring and floating microplastic in a coastal area of Indonesia.

Qualitative analysis of the structures of the polymers composing floating plastic debris was performed using attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and the aging of the debris was assessed by measuring carbonyl group formation on the particle surfaces. Plastic material made up >75% of the 2313 items collected during a three-year survey. The size, shape and color of the microplastic were correlated with the polymer structure.