Two distinct Ag/Au nanocomposites, namely, hetero-oligomers and eccentric core/shells were obtained by one-step polymer self-assembly-based fabrication. The Ag concentration-dependent, facet-specific passivation, and presence or absence of anisotropic facets were the main factors responsible for controlling the structures of the final products. Based on an understanding of the role of Ag ions in controlling the shape of anisotropic gold nanoparticles (AuNPs), tailored concentrations of Ag were applied to design nanoparticles with desired anisotropic surface facets to allow site-specific Ag coatings on AuNPs.
View Article and Find Full Text PDFIn this study, we fabricated a hybrid plasmonic/semiconductor material by combining the chemical bath deposition of zinc oxide nanowires (ZnONWs) with the physical vapor deposition of aluminum nanostructures (AlNSs) under controlled temperature and atmosphere. The morphological and the optical properties of the ZnONWs/AlNSs hybrid material fabricated at different temperatures (250, 350, and 450 °C) and thicknesses (5, 7, and 9 nm) of Al layers were investigated. By adjusting the deposition and annealing parameters, it was possible to tune the size distribution of the AlNSs.
View Article and Find Full Text PDFThis work describes a novel, one-shot strategy to fabricate ultrasensitive SERS sensors based on silver/poly(methyl methacrylate) (PMMA) nanocomposites. Upon spin coating of a dispersion of PMMA and silver precursor on N-doped silicon substrate, closely separated silver nanoparticles were self-assembled into uniform nanospheres. As a result, a thin hydrophobic PMMA layer embedded with Ag nanoparticles (AgNPs) was obtained on the whole silicon substrate.
View Article and Find Full Text PDFOne of the key issues for SERS-based trace applications is engineering structurally uniform substrates with ultrasensitivity, stability, and good reproducibility. A label-free, cost-effective, and reproducible fabrication strategy of ultrasensitive SERS sensors was reported in this work. Herein, we present recent progress in self-assembly-based synthesis to elaborate precisely shaped and abundant gold nanoparticles in a large area.
View Article and Find Full Text PDFThe optical properties of a monolayer of nanocomposite film (PMMA/gold nanocubes) were provided by fitting a proposed theoretical model to spectroscopic ellipsometry (SE) measurements. For such a thin film, these features cannot be successfully determined by means of experimental and conventional effective medium theory such as Maxwell-Garnett or Bruggeman. To make it possible, we developed a model of two classical Lorentz oscillators; one for a PMMA layer and the other for GNCs, revealing one homogeneous layer and rapid analysis without the need for large computational resources.
View Article and Find Full Text PDFWe show femtosecond direct laser-induced assembly of gold nanostructures with plasmon resonance band variable as a function of laser irradiation in a wide range of visible wavelengths. A system of 2-photon lithography is used to achieve site-selectively controlled dewetting of a thin gold film into nanostructures in which size and shape are highly dependent on the laser power. Simultaneous measurements of localized surface plasmon resonance (LSPR) and surface enhanced Raman scattering (SERS) in the presence of various concentrations of trans-1,2-bis(4-pyridyl) ethylene (BPE) as target molecule are performed in order to highlight the relationship between structural dimensions, plasmonic effect, and detection activity.
View Article and Find Full Text PDFAn ellipsometric cell is developed to simultaneously determine the shape distribution, the volume fraction, and the complex refractive index of gold and silver colloids. Simulation reveals that this cell drastically improves the detection limit of ellipsometry. Indeed, Ag and Au nanoparticles (NPs) are detected at the ppmv level.
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