Back electron transfer rates determine the photoreactivity of donor-acceptor stilbene complexes in a macrocyclic host.

Host-guest 2 : 1 complexation of photoreactive alkene guests improves the selectivity of [2 + 2] photodimerizations by templating alkene orientation prior to irradiation. Host-guest chemistry can also provide 1 : 1 : 1 complexes through the inclusion of electronically complementary donor and acceptor guests, but the photoreactivity of such complexes has not been investigated. We imagined that such complexes could enable selective cross-[2 + 2] photocycloadditions between donor and acceptor stilbenes.

Mechanistic Investigation of Molybdenum Disulfide Defect Photoluminescence Quenching by Adsorbed Metallophthalocyanines.

Lattice defects play an important role in determining the optical and electrical properties of monolayer semiconductors such as MoS. Although the structures of various defects in monolayer MoS are well studied, little is known about the nature of the fluorescent defect species and their interaction with molecular adsorbates. In this study, the quenching of the low-temperature defect photoluminescence (PL) in MoS is investigated following the deposition of metallophthalocyanines (MPcs).

Enhanced Exciton Quantum Coherence in Single CsPbBr Perovskite Quantum Dots using Femtosecond Two-Photon Near-Field Scanning Optical Microscopy.

Cesium-halide perovskite quantum dots (QDs) have gained tremendous interest as quantum emitters in quantum information processing applications due to their optical and photophysical properties. However, engineering excitonic states in quantum dots requires a deep knowledge of the coherent dynamics of their excitons at a single-particle level. Here, we use femtosecond time-resolved two-photon near-field scanning optical microscopy (NSOM) to reveal coherences involving a single cesium lead bromide perovskite QD (CsPbBr) at room temperature.

Tunable Broad Light Emission from 3D "Hollow" Bromide Perovskites through Defect Engineering.

Hybrid halide perovskites consisting of corner-sharing metal halide octahedra and small cuboctahedral cages filled with counter cations have proven to be prominent candidates for many high-performance optoelectronic devices. The stability limits of their three-dimensional perovskite framework are defined by the size range of the cations present in the cages of the structure. In some cases, the stability of the perovskite-type structure can be extended even when the counterions violate the size and shape requirements, as is the case in the so-called "hollow" perovskites.

Light-Triggered Switching of Quantum Dot Photoluminescence through Excited-State Electron Transfer to Surface-Bound Photochromic Molecules.

This paper describes reversible "on-off" switching of the photoluminescence (PL) intensity of CdSe quantum dots (QDs), mediated by photochromic furylfulgide carboxylate (FFC) molecules chemisorbed to the surfaces of the QDs. Repeated cycles of UV and visible illumination switch the FFC between "closed" and "open" isomers. Reversible switching of the QDs' PL intensity by >80% is enabled by different rates and yields of PL-quenching photoinduced electron transfer (PET) from the QDs to the respective isomers.

Tailoring the Optical Response of Pentacene Thin Films via Templated Growth on Hexagonal Boron Nitride.

The optoelectronic properties of organic thin films are strongly dependent on their molecular orientation and packing, which in turn is sensitive to the underlying substrate. Hexagonal boron nitride (hBN) and other van der Waals (vdW) materials are known to template different organic thin film growth modalities from conventional inorganic substrates such as SiO. Here, the morphology and temperature-dependent optical properties of pentacene films grown on hBN are reported.

Low energy excited state vibrations revealed in conjugated copolymer PCDTBT.

Low energy vibrations in the excited state have been hypothesized to play an important role in quickly and efficiently generating free charges in bulk heterojunctions of some conjugated polymer systems. While time-resolved vibrational spectroscopies seemingly are well poised to address the relationship between kinetics and vibrational motions after initial photoexcitation, uncertainty in the measurement arises due to overlapping signals and difficulties in assigning observed oscillatory signals to the molecular response. Here, we demonstrate a high sensitivity strategy to distinguish between signal oscillations originating from lab noise and those molecular in origin in order to isolate the low energy excited-state vibrations in the model conjugated copolymer PCDTBT.

Emergent Optoelectronic Properties of Mixed-Dimensional Heterojunctions.

ConspectusThe electronic dimensionality of a material is defined by the number of spatial degrees of confinement of its electronic wave function. Low-dimensional semiconductor nanomaterials with at least one degree of spatial confinement have optoelectronic properties that are tunable with size and environment (dielectric and chemical) and are of particular interest for optoelectronic applications such as light detection, light harvesting, and photocatalysis. By combining nanomaterials of differing dimensionalities, mixed-dimensional heterojunctions (MDHJs) exploit the desirable characteristics of their components.

Photoinduced charge recombination in dipolar D-A-A photonic liquid crystal polymorphs.

A hexylalkoxy dipolar D-A-A molecule [7-(4-N,N-(bis(4-hexyloxyphenyl)amino)phenyl)-2,1,3-(benzothia-diazol-4-yl)methylene]propane-dinitrile, (C6-TPA-BT-CN) has been synthesized and the photophysics studied via femtosecond transient absorption spectroscopy (FsTA) in toluene and in amorphous and liquid crystalline spherulite thin films. Two spherulite macromolecular crystalline phases (banded, and non-banded) were observed through concentration dependent, solution processing techniques and are birefringent with a negative sign of elongation. A dramatic change in the electronic absorption from blue in amorphous films to green in spherulites was observed, and the molecular orientation was determined through the combined analysis of polarized light microscopy, X-ray diffraction, and scanning electron microscopy.

Human Fanconi anemia complementation group a protein stimulates the 5' flap endonuclease activity of FEN1.

In eukaryotic cells, Flap endonuclease 1 (FEN1) is a major structure-specific endonuclease that processes 5' flapped structures during maturation of lagging strand DNA synthesis, long patch base excision repair, and rescue of stalled replication forks. Here we report that fanconi anemia complementation group A protein (FANCA), a protein that recognizes 5' flap structures and is involved in DNA repair and maintenance of replication forks, constantly stimulates FEN1-mediated incision of both DNA and RNA flaps. Kinetic analyses indicate that FANCA stimulates FEN1 by increasing the turnover rate of FEN1 and altering its substrate affinity.