Organic BODIPY based gels: Optical, electrochemical and self-assembly properties.

Two novel BODIPY dyes, BOC3 and BC12, were synthesized with variable alkyl chains at terminal amide functional units. BC12, featuring a longer alkyl chain (-C12H25), formed a gel compared to BOC3, which has a shorter alkyl chain (-CH2OCH3), due to supra molecular self-assembly in film. Both dyes exhibited absorption peaks around 530 nm in the visible region, with a red shift of about 30 nm in the film state, essential for organic electronic applications.

Ambipolar macrocycle derived from spiro-xanthene and carbazole: synthesis, structure-property relationships, electronic properties and host-guest investigation.

For the first time, we present the detailed synthesis, photophysical, electrochemical, host-guest and charge transport properties of spiro[fluorene-9,9'-xanthene] (SFX) and carbazole macrocycle SPS-NR-02. The electron and hole transport values measured using the space charge limited current (SCLC) method resulted in ambipolar charge transport with an electron to hole mobility ratio of 0.39.

Excited Charge Separation in a π-Interacting Phenothiazine-Zinc Porphyrin-Fullerene Donor-Acceptor Conjugate.

We have designed, synthesized, and characterized a donor-acceptor triad, , that consists of a π-interacting phenothiazine-linked porphyrin as a donor and sensitizer and fullerene as an acceptor to seek charge separation upon photoexcitation. The optical absorption spectrum revealed red-shifted Soret and Q-bands of porphyrin due to charge transfer-type interactions involving the two ethynyl bridges carrying electron-rich and electron-poor substituents. The redox properties suggested that the phenothiazine-porphyrin part of the molecule is easier to oxidize and the fullerene part is easier to reduce.

Molecularly Engineered Multifunctional Bridging Layer Derived from Dithiafulavene Capped Spiroxanthene for Stable and Efficient Perovskite Solar Cells.

This study introduces a novel approach centered around the design and synthesis of an interfacial passivating layer in perovskite solar cells (PSCs). This architectural innovation is realized through the development of a specialized material, termed dithiafulvene end-capped Spiro[fluorene-9,9'-xanthene], denoted by the acronym AF32. In this design architecture, dithiafulvene is thoughtfully attached to the spiroxanthene fluorene core with phenothiazine as the spacer unit, possessing multiple alkyl chains.

BODIPY-Based Mitochondrial Targeted NIR-Responsive CO-Releasing Platform for the On-Demand Release of CO to Treat Cancer.

It is an established fact that cancer is one of the most serious public health issues after coronary artery disease. Thus, exploring more effective and efficient therapeutic protocols over the traditional chemotherapeutic strategy is imperative to improving cancer survivorship and patient quality of life. In this respect, recent reports on molecularly engineered -substituted BODIPY have shown remarkable effects as a photoresponsive CO-releasing platform for the on-demand release of CO to treat cancer.

Fullerene C as Photoredox Catalyst for the Synthesis of Pyrrolo[2,1-a]isoquinolines by 1,3-Dipolar Cycloaddition-Aromatization Sequence.

Herein, fullerene (C ) is introduced as an effective photoredox catalyst for the construction of a highly functionalised pyrrolo[2,1-a]isoquinoline framework by 1,3-dipolar cycloaddition-aromatisation reaction sequence. The ability of C to efficiently harvest visible light, its long-triplet state lifetime, good photostability, and strong singlet oxygen generation potential (Φ ≈1), make it an efficient photoredox catalyst. Upon photoirradiation, C promotes the formation of singlet oxygen and superoxide radical by energy transfer (EnT) and single electron transfer (SET) mechanism.

Photocatalyst-free visible-light triggered amination of benzo[][1,2,5]thiadiazole: direct C-N bond formation from C(sp)-H bond.

The photoredox amination of arene protocols mostly comprises photocatalyst-mediated transformations. Herein, we presented the photocatalyst-free, visible-light promoted, direct conversion of C(sp)-H to C(sp)-N method. Multipurpose benzothiadiazoles are used as model synthons and secondary amines as aminating agents.

Phenothiazine functionalized fulleropyrrolidines: synthesis, charge transport and applications to organic solar cells.

A series of phenothiazine-C dyads containing fulleropyrrolidine tethered to C-3 position (C-PTZ and C-PTZ) or to the heteroatom N-position via either phenyl (C-Ph-PTZ and C-Ph-PTZ) or phenoxyethyl linkers (C-PhOEt-PTZ and C-PhOEt-PTZ) of the phenothiazine were synthesized and light-induced electron transfer events were explored. Optimized studies suggested that the highest molecular orbital (HOMO) resides on donor phenothiazine moiety while lowest molecular orbital (LUMO) on the acceptor fulleropyrrolidine moiety of the dyads. Optical and electrochemical properties suggested no electronic communication between the donor and acceptor moieties in the ground state.

Two phase algorithm for bi-objective relief distribution location problem.

The location planning of relief distribution centres (DCs) is crucial in humanitarian logistics as it directly influences the disaster response and service to the affected victims. In light of the critical role of facility location in humanitarian logistics planning, the study proposes a two-stage relief distribution location problem. The first stage of the model determines the minimum number of relief DCs, and the second stage find the optimal location of these DCs to minimize the total cost.

[1]Benzothieno[3,2-][1]benzothiophene-based dyes: effect of the ancillary moiety on mechanochromism and aggregation-induced emission.

It is an established fact that [1]benzothieno[3,2-][1]benzothiophene (BTBT) is a champion molecule for high-mobility OFET devices. Recently, it has also been utilized in dye-sensitized solar cells (DSSCs) and organic photovoltaics (OPVs) as an alternative to fullerene (non-fullerene acceptor). Considering the advantageous features of BTBT, we herein report its aggregation-induced emission (AIE) and mechanofluorochromic (MFC) behaviour for the first time.

Enhanced permeability and retention effect: A key facilitator for solid tumor targeting by nanoparticles.

Exploring the enhanced permeability and retention (EPR) effect through therapeutic nanoparticles has been a subject of considerable interest in tumor biology. This passive targeting based phenomenon exploits the leaky blood vasculature and the defective lymphatic drainage system of the heterogeneous tumor microenvironment resulting in enhanced preferential accumulation of the nanoparticles within the tumor tissues. This article reviews the fundamental studies to assess how the EPR effect plays an essential role in passive targeting.

Efficient Medium Bandgap Electron Acceptor Based on Diketopyrrolopyrrole and Furan for Efficient Ternary Organic Solar Cells.

We report the design of novel medium bandgap nonfullerene small molecule acceptor NFSMA with A-π-A-π-A architecture, with the molecular engineering of this material comprising a strong electron-accepting backbone unit DPP (A) as the acceptor, which is attached to the dicyanomethylene-3-hexylrhodanine (A) acceptor via a furan (π-spacer) linker. We systematically studied its structural and optoelectronic properties. The incorporation of dicyanomethylene-3-hexylrhodanine and furan enhance the light absorption and electrochemical properties by extending π-conjugation and is anticipated to improve by decreasing the LUMO level.

Aza-dipyrrinato ruthenium sensitizers for enhancement of Light-Harvesting ability of Dye-Sensitized solar cells.

Three new aza-dipyrrinato ruthenium sensitizers AZA-BPY, AZA-BPY-NCS, and AZA-TER, have been designed and successfully synthesized. We have studied the effect of aza-dipyrrinato ligands on the photo-physical and electrochemical properties. The aza-dipyrrinato ancillary ligand exhibited enhancement in the light-harvesting capability compared to the traditional dipyrrinato ligand by coordinating ruthenium metal.

Multi-echelon agri-food supply chain network design integrating operational and strategic objectives: a case of public distribution system in India.

The global concern to ensure the availability of food for the growing world's population draws urgent attention towards the inefficiencies in agri-food supply chains. Agri-food supply chains are inherently complex to manage than other supply chains mainly because of their multi-echelon structure, deteriorating product quality with time and changes in storage conditions which leads to significant amount of food loss and wastage. Additionally, any natural or man-made disaster further disrupts the chain and leads to high food loss, high supply chain costs, reduced food availability and poor food quality.

Selection of healthcare waste disposal firms using a multi-method approach.

The aim of this study is to propose a hybrid multi criteria decision making model with a linear programming (LP) model to tackle the issue of safe disposal of hazardous and infectious healthcare waste. For this, ten criteria in this study have been identified from literature and field surveys which are modelled using Decision making trial and evaluation (DEMATEL) and Analytic network process (ANP) methods to select the best disposal firm i.e.

Near-Infrared (>1000 nm) Light-Harvesters: Design, Synthesis and Applications.

Organic molecules can absorb or emit light in UV, visible and infra-red (IR) region of solar radiation. Fifty percent of energy of solar radiation lies in the IR region of solar spectrum and extended π-conjugated molecules containing low optical band gap can absorb NIR radiations. Recently IR molecules have grabbed the attention of synthetic chemists.

Lead-halides Perovskite Visible Light Photoredox Catalysts for Organic Synthesis.

Lead-halide perovskites has grabbed great attention in recent years due to its unique photophysical and electrical properties. It has open new window in organic solar cell application for commercial point. Research has extended its application further towards visible light photoredox catalysts for organic synthesis.

Designing dynamic reverse logistics network for post-sale service.

The paper addresses the problem of designing a multi-country production-distribution network that also provides services such as repairs and remanufacturing. The proposed work concentrates primarily on post-sale service provided by the firm under warranty returns. The proposed model assumes that existing warehouses can also serve as collection centres or repair centres for reverse logistics.

Lead-Free, Water-Stable A Bi I Perovskites: Crystal Growth and Blue-Emitting Quantum Dots [A=CH NH , Cs , and (Rb Cs ) ].

Despite the great success in the increase in the power conversion efficiency of lead halide perovskite solar cells, the toxicity of lead and the unstable nature of the materials are still major concerns for their wider implementation at the industrial level. Herein, large-size single crystals (SCs) are developed in HI solution by using a temperature lowering method and nanocrystals (NCs) of A Bi I perovskites [where A=CH NH (MA) , Cs , and (Rb Cs ) ] are formed in ethanol (EtOH) and toluene (TOL). The stability of A Bi I perovskite is investigated by immersing the SCs for 24 h and pellets for 12 h in water.

Phenothiazine-Based Hole Transport Materials for Perovskite Solar Cells.

The promising photovoltaic solar cells based on the perovskite light-harvesting materials have attracted researchers with their outstanding power conversion efficiencies (over 23% certified). The perovskite work has geared up in just under a decade and is competing with well-established semiconductor technologies such as silicon (Si), copper indium gallium selenide (CIGS), and cadmium telluride (CdTe). To commercialize the perovskite solar cells, their stability is the major concern.

Spoof surface plasmonic transmission line with high isolation and low propagation loss.

A novel compact spoof surface plasmonic (SSP) transmission line (TL) consisting of a stem-shaped periodic structure is proposed to achieve high field confinement in the higher frequency range (microwave to terahertz). The dispersion characteristic of the proposed stem-shaped SSP unit cell exhibits much lower asymptotic frequency and higher field confinement than the conventional coplanar waveguide (CPW) and the rectangular SSP unit cell structure without increasing the overall transverse dimension, i.e.

Distribution network model using big data in an international environment.

This paper proposes dynamic mixed integer facility location model to design an international manufacturing network (IMN). The proposed model considers a broad facility network linking production and distribution facilities located internationally. The proposed model discussed in the paper assumes significance over the traditional manufacturing model as it provides a country specific analysis making it more convenient for the decision maker to devise country specific strategies within an international ecosystem.

Ni-Doped CsPbBr Perovskite: Synthesis of Highly Stable Nanocubes.

A nanocube of Ni-doped CsPbBrnanocrystals (NCs) has been successfully synthesized and characterized by various spectroscopy techniques such as High-resolution transmission electron microscopy (HR-TEM), field emission scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS), etc. The optoelectronic properties of NCs have been investigated with different solvents. HR-TEM and FE-SEM reveal that the obtained Ni-doped CsPbBrNCs exhibit cubic-rectangular morphologies with different sizes.

Butterfly architecture of NIR Aza-BODIPY small molecules decorated with phenothiazine or phenoxazine.

This is the first report on the highest efficiency NIR absorbing Aza-Bodipy small molecules. The molecular engineering of newly synthesized NIR absorbing Aza-Bodipy dyes consists of covalently linked phenothiazine (AZA-PTZ-BOD) and phenoxazine (AZA-POZ-BOD) moieties as terminal groups and Aza-Bodipy as a central core moiety. The highest efficiency for OPV devices of 8.

Impact of A-D-A-Structured Dithienosilole- and Phenoxazine-Based Small Molecular Material for Bulk Heterojunction and Dopant-Free Perovskite Solar Cells.

Herein, the synthesis of the novel acceptor-donor-acceptor (A-D-A)-structured small molecule Si-PO-2CN based on dithienosilole (DTS) as building block flanked by electron-rich phenoxazine (POZ) units, which are terminated with dicyanovinylene, is presented. Si-PO-2CN showed unique electrochemical and photophysical properties and has been successfully employed in perovskite solar cells (PSCs) as well as in bulk heterojunction organic solar cells (OSCs). The PSCs fabricated with dopant-free Si-PO-2CN as hole-transport material (HTM) exhibited a power conversion efficiency (PCE) of 14.