An experimental study was carried out to develop and examine the properties of a new type of structural insulated panel (SIP). SIP prototypes conducted from this research consisted of insulated foam manufactured from natural rubber filled with wood particles as the core layer and three kinds of commercial wood-composite boards (plywood, cement particleboard, and fiber-cement board) as the surface layers. Polyurethane was used as an adhesive bond between the surface and the core layer.
View Article and Find Full Text PDFSurface modification of 1,4-polybutadiene and cis-1,4-polyisoprene to introduce polar functional groups provided surfaces that reconstructed reversibly against water as a function of temperature. These surfaces became hydrophobic in contact with hot water, but their original hydrophilicity returned upon equilibration against cold water. Repeated cycling between hot and cold water, however, led to a damping of this reversibility.
View Article and Find Full Text PDFThe study of adhesion has a long and rich history, with theory, experiments, and applications bridging numerous disciplines, including physics, chemistry, engineering, and medicine. This diverse interest has led to the development of a large number of methods for both enhancing and inhibiting adhesion at specific interfaces of interest. We report herein "smart" adhesion at a polymer/metal (oxide) interface that responds reversibly to changes in temperature by increasing or decreasing in magnitude.
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