Publications by authors named "Suresh M Tuwar"

The present study involves detecting and determining CIP by a new electrochemical sensor based on graphene (Gr) in the presence of sodium dodecyl sulfate (SDS) employing voltammetric techniques. Surface morphology studies of the sensing material were analyzed using a scanning electron microscope (SEM) and atomic force microscope (AFM). In the electroanalysis of CIP at the developed electrode, an enhanced anodic peak response was recorded, suggesting the electro-oxidation of CIP at the electrode surface.

View Article and Find Full Text PDF

The antibiotic drug trimethoprim (TMP) is used to treat bacterial infections in humans and animals, and frequently TMP is used along with sulfonamides. However, a large portion of TMP is excreted in its active state, which poses a severe problem to humans and the environment. A sensitive, rapid, cost-effective analytical tool is required to monitor the TMP concentration in biological and environmental samples.

View Article and Find Full Text PDF

In this research, detection of trimethoprim (TMP) was carried out using a nanostructured zinc oxide nanoparticle-modified carbon paste electrode (ZnO/CPE) with an anionic surfactant and sodium dodecyl sulphate (SDS) with the help of voltametric techniques. The electrochemical nature of TMP was studied in 0.2 M pH 3.

View Article and Find Full Text PDF

The electrochemical analysis of theophylline (THP) was investigated by fabricating a carbon paste electrode (CPE) modified with graphene oxide (GO) along with copper oxide (CuO) nanoparticles (CuO-GO/CPE). The impact of electro-kinetic parameters such as the heterogeneous rate constant, the scan rate, the accumulation time, the pH, the transfer coefficient, and the number of electrons and protons transferred into the electro-oxidation mechanism of THP has been studied utilizing electrochemical methods such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The differential pulse voltammetry technique was employed to investigate THP in pharmaceutical and biological samples, confirming the limit of detection (LOD) and quantification (LOQ) of the THP.

View Article and Find Full Text PDF

Abstract: Kinetics of Permanganate (MnO ) oxidation of antiviral drug, valacyclovir hydrochloride (VCH) has been studied spectrophotometrically at a constant ionic strength of 0.1 mol dm. The reaction exhibiting a 2:1 stoichiometry (MnO :VCH) has been studied over a wide range of experimental conditions.

View Article and Find Full Text PDF

In agro-areas, linuron (LNR) and amino-triazole (ATZ) are the widely used herbicides to protect crops, but their widespread use pollutes the environment, especially when these are mixed with water or soil. In efforts to address these environmental issues and to detect trace quantities of the herbicides, a graphitic carbon nitride (g-CN) with cetyltrimethylammonium bromide (CTAB) modified carbon paste electrode (g-CN-CTAB/CPE) was developed and used for the detection of LNR and ATZ. Materials were characterized by XRD, TEM and AFM techniques.

View Article and Find Full Text PDF

The absorption and fluorescence spectra of synthesized 4-[5-(2,5-Dimethyl-pyrrol-1-yl)-[1, 3, 4] thiadiazol-2-ylsulfanylmethyl]-6-methoxy-chromen-2-one (DTYMC) compound were recorded in various solvents like acetone, acetonitrile, chloroform, dimethyl formamide (DMF),1,4-dioxane, ethanol, ethyl acetate, methanol, tetrahydrofuran (THF) and dimethylsulphoxide (DMSO) at room temperature in order to estimate the ground and excited state dipole moment. The ground state dipole moment (μ) and excited state dipole moment (μ) were calculated using solvatochromic shift method which involve equations proposed by Lippert, Bakshiev and Kawski-Chamma-Viallete. The results were signified that the excited state dipole moment is greater than the ground state dipole moment, which indicates the excited state is more polar than the ground state of the molecule.

View Article and Find Full Text PDF