Cobalt-Copper-Embedded Nitrogen-Doped Carbon Nanostructures Derived from Zeolite Imidazolate Frameworks as Electrocatalysts for the Oxygen Reduction Reaction.

In recent years, researchers have focused on developing zeolite imidazolate frameworks (ZIFs) as an alternative to Pt electrocatalysts for various applications, including water splitting, lithium-air batteries, zinc-air batteries, and fuel cells. In this study, we synthesized CoCu-ZIF to be used as a precursor in the development of cathode catalysts for the oxygen reduction reaction (ORR) in fuel cells. Hydrazine played a crucial role in maintaining uniformity in the development and particle size of the ZIF-67 structures.

Low content Ru-incorporated Pd nanowires for bifunctional electrocatalysis.

This paper reports the facile synthesis and characterization of carbon supported Pd nanowires with low Ru contents (nRuPd/C). An anti-galvanic replacement reaction involving the reduction of Ru(iii) ions by nanoporous Pd nanowires to form nRuPd alloy nanowires was observed. A series of nRuPd/C materials with various Ru/Pd ratios were prepared by the spontaneous deposition of a Ru cluster on a Pd nanowire core using different Ru precursor concentrations (RuCl = 0.

Photochemical Approach for the Preparation of N-Alkyl/Aryl Substituted Fulleropyrrolidines: Photoaddition Reactions of Silyl Group Containing α-Aminonitriles with Fullerene C.

The photochemical reactions of C with N-(trimethylsilyl)methyl substituted and N-alkyl/aryl substituted α-aminonitriles were explored to evaluate the scope and reaction efficiency depending on the structural nature of amine substrates. The results showed that photoreactions of C with trimethylsilyl group containing N-alkyl amines produced predominantly both trimethylsilyl and cyano group containing trans-pyrrolidine ring fused fulleropyrrolidines in a chemo- and stereoselective manner. Interestingly, photoreactions of C with N-branched alkyl substituted amines led to exclusive formation of non-silyl containing cycloadducts.