Fe-Ni Diatomic Sites Coupled with Pt Clusters to Boost Methanol Electrooxidation via Free Radical Relaying.

Pt-based catalysts for direct methanol fuel cells (DMFCs) are still confronted with the challenge of over-oxidation of Pt and poisoning effect of intermediates; therefore, a spatial relay strategy was adopted to overcome these issues. Herein, Pt clusters were creatively fixed on the N-doped carbon matrix with rich Fe-Ni diatoms, which can provide independent reaction sites for methanol oxidation reaction (MOR) and enhance the catalytic activity due to the electronic regulation effect between Pt cluster and atomic-level metal sites. The optimized Pt/FeNi-NC catalyst shows MOR electrocatalytic activity of 2.