A near-infrared (NIR) organic probe for rapid naked-eye detection of fluoride ions in aqueous medium.

A dihydroxy-substituted tricyanopyrroline-based near-infrared (NIR) colorimetric probe (TCP-34Hy) is developed for the effective detection of fluoride ions in aqueous medium in the presence of Ca ions. The naked-eye detection (drastic color change) selectively makes the NIR colorimetric sensor more efficient. The probe can detect fluoride ions from inorganic sources (NaF/KF) as well as organic sources (TBAF) in water.

Effect of various aqueous extracting agents on fluorescence properties of waste tea residue derived carbon dots (WTR-CDs): Comparative spectroscopic analysis.

Fluorescent carbon dots (CDs) are one of the important carbonaceous nanomaterials in the area of nanoscience and nanotechnology because of their interesting physical as well as chemical properties. Herein we studied the effect of various aqueous extracting agents on fluorescence properties of waste tea residue-based carbon dots (WTR-CDs). WTR-CDs are firstly synthesized by utilizing kitchen waste-based carbonaceous biomass.

Applications of Carbon Dots (CDs) in Latent Fingerprints Imaging.

Carbon dots (CDs), a new member of the carbon-based material family, possess unique properties, such as high fluorescence, non-toxicity, eco-friendliness, stability and cost-effectiveness. These properties helped CDs to receive tremendous attention in various fields, namely, biological, opto-electronic, bio-imaging and energy-related applications. Although CDs are widely explored in bio-imaging and bio-sensing applications, their effectiveness in forensic science and technology is comparatively new.

Coordination-Assisted Reversible Photoswitching of Spiropyran-Based Platinum Macrocycles.

Control over the stimuli-responsive behavior of smart molecular systems can influence their capability to execute complex functionalities. Herein, we report the development of a suite of spiropyran-based multi-stimuli-responsive self-assembled platinum(II) macrocycles (-), rendering coordination-assisted enhanced photochromism relative to the corresponding ligands. showed shrinking and swelling during photoreversal, while and are fast and fatigue-free supramolecular photoswitches.

J-type aggregation and thermochromic behavior of a schiff base in solution: Role of keto-enol tautomerization.

In present work, we have been investigated the thermochromism, keto-enol tautomerization, J-type aggregation and aggregation induced enhanced fluorescence (AIEF) in a single schiff base molecule (HNBzP) along with excited state intramolecular proton transfer (ESIPT) process. It is observed that keto-enol tautomerization plays an important role on thermochromism, J-type aggregation and aggregation induced enhanced fluorescence (AIEF) process in solution. From UV-Vis and fluorescence studies, J-type aggregation is observed and shows the aggregation induce enhanced fluorescence (AIEF) behaviour in solusion.

Cluster Formation through Hydrogen Bond Bridges across Chloride Anions in a Hydroxyl-Functionalized Ionic Liquid.

Several recent studies of hydroxyl-functionalized ionic liquids (ILs) have shown that cation-cation interactions can be dominating these materials at the molecular level when the anion involved is weakly interacting. The hydrogen bonds between the like ions led to the formation of interesting chain-like, ring-like, or distinct dimeric (i. e.

Temperature sensor probe based on intramolecular charge transfer (ICT) & reversible solute-solvent interaction in solution.

In this present work, we have developed a temperature sensitive ICT probe (KNP) to investigate alternation of ICT process with the temperature in polar protic solvents. The H-bonding interaction is found to play a key role on solute-solvent interaction to become a temperature sensitive ICT probe in solution. From temperature dependent UV-Vis spectra, it is cleared that the solute-solvent interaction is reversible in nature with temperature and affected by concentration in polar protic solvents.

Clusters of the Ionic Liquid 1-Hydroxyethyl-3-methylimidazolium Picrate: From Theoretical Prediction in the Gas Phase to Experimental Evidence in the Solid State.

Interonic interactions determine the macroscopic properties of ionic liquids (ILs). Hence, unravelling the relationships between the microscopic and macroscopic scales is key for rational design. Combining density functional theory (DFT) calculations of isolated ion pairs and vibrational spectroscopy of the condensed phase (fluid or solid) has become a very common approach.

Evidence of C--F-P and aromatic π--F-P weak interactions in imidazolium ionic liquids and its consequences.

A simple change from alkyl group to alkene in side chain of imidazolium cation with same anion resulted in a drastic impact on physical properties (e.g., melting point) from bmimPF IL to cmimPF IL.

Microheterogeneity in imidazolium and piperidinium cation-based ionic liquids: 1D and 2D NMR studies.

Existence of microheterogeneity of imidazolium and piperidinium cation-based ionic liquids (ILs) containing PF and NTf anions has been investigated by 1D and 2D NMR spectroscopy. 2D NMR (especially NOESY and HOESY) has been employed for studying the interactions present between cation and anion as well as the intermolecular interaction among cations. HOESY spectrum shows that fluorine of anion ( PF6- and NTf2-) significantly interacts with proton of the cations.

Manipulating the proton transfer process in molecular complexes: synthesis and spectroscopic studies.

The proton transfer process in carefully designed molecular complexes has been investigated directly in the solid and solution phase. SCXRD studies have been employed to investigate the N-H-O bonding interaction sites of the molecular complexes, with additional experimental support from FTIR and Raman spectroscopic studies, to gain information on the relative position of hydrogen in between the N and O centers. Further, the proton transfer process in solution is studied using UV-Visible spectroscopy through monitoring the intramolecular charge transfer (ICT) process in these molecular complexes, which is primarily governed by the number of electron withdrawing groups (nitro groups) on proton donor moieties (NP, DNP and TNP).

Anion directed structural diversity in zinc complexes with conformationally flexible quinazoline ligand: structural, spectral and theoretical studies.

In this paper, we report the synthesis, structure and photophysical studies of four new complexes of conformationally flexible 6-chloro-4-phenyl-2-(pyridin-2-yl)quinazoline ligand (L) with Zn(ii). The coordinating ability of the ligand and geometrical preferences of the resultant complexes are tuned by varying the anion of the metal salt as confirmed by structural and DFT studies. The choice of the metal salt (especially anion) directs the stabilisation of different conformations of the ligand arising out of twisting of the pyridyl ring with respect to the quinazoline ring, resulting in complexes with different nuclearity (monomer/dimer) as well as different coordination geometries (tetrahedral/trigonal bipyramidal/octahedral).

Significance of weak interactions in imidazolium picrate ionic liquids: spectroscopic and theoretical studies for molecular level understanding.

The effects of interionic hydrogen bonding and π-π stacking interactions on the physical properties of a new series of picrate anion based ionic liquids (ILs) have been investigated experimentally and theoretically. The existence of aromatic (C2-HO) and aliphatic (C7-HO-N22 and C6-HO-N20) hydrogen bonding and π-π stacking interactions in these ILs has been observed using various spectroscopic techniques. The aromatic and aliphatic C-HO hydrogen bonding interactions are found to have a crucial role in binding the imidazolium cation and picrate anion together.