Publications by authors named "Sumesh Ck"

The main challenge for water electrolysis is that continuous and effective hydrogen evolution at high current densities is unattainable due to the quick degradation of performance that occurs with extended large-current operation. In this work, sulfur-doped nickel ferrite nanocomposites were prepared using simple hydrothermal method with the objective of improving electrocatalytic green hydrogen production at industrial current densities. X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were used to analyse the crystalline structure, morphology, and chemical composition of the synthesised nanocomposites.

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Article Synopsis
  • Polymeric carbon nitride (PCN) and its nanocomposite with zinc oxide (ZnO) are being studied for their potential to enhance hydrogen evolution reactions (HER), but their efficiency needs improvement.
  • The research developed two synthesis methods for the PCN-ZnO nanocomposites, with Method 1 yielding a more effective catalyst for both hydrogen and oxygen production due to a favorable energy gap and smaller particle size.
  • Results indicate that the PCN-ZnO nanocomposite from Method 1 significantly outperformed pristine PCN and ZnO in HER and exhibited four times greater solar-to-hydrogen efficiency, highlighting its promise for sustainable energy applications.
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  • The development of a cost-effective V-NiS catalytic network on nickel foam aims to enhance green hydrogen production through improved water and urea electrolysis.
  • The morphology of the catalyst is optimized by varying vanadium concentrations, which promotes better charge transport and increases active sites for reactions.
  • The V-NiS catalyst demonstrates impressive performance metrics, requiring lower voltage for generating current and sustaining stability over extended periods, indicating its potential for industrial applications in hydrogen generation.
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Several studies on semiconductor material-based single-band, high-performance photosensitive, and chemically stable photodetectors are available; however, the lack of broad spectral response, device flexibility, and biodegradability prevents them from being used in wearable and flexible electronics. Apart from that, the selection of the device fabrication technique is a very crucial factor nowadays in terms of equipment utilization and environmental friendliness. This report presents a study demonstrating a straightforward solvent- and equipment-free handprint technique for the fabrication of WSe-TiCT flexible, biodegradable, robust, and broadband (Vis-NIR) photodetectors.

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Recently, there has been a huge research interest in developing robust, efficient, low-cost, and earth-abundant materials for water and urea electrolysis for hydrogen (H) generation. Herein, we demonstrate the facile hydrothermal synthesis of self-supported Mn-NiSe on Ni foam for overall water splitting under wide pH conditions. With the optimized concentration of Mn in NiSe, the overpotential for hydrogen evolution, oxygen evolution, and urea oxidation is significantly reduced by an enhanced electrochemical active surface area.

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A viable alternative to non-renewable hydrocarbon fuels is hydrogen gas, created using a safe, environmentally friendly process like water splitting. An important role in water-splitting applications is played by the development of two-dimensional (2D) layered transition metal chalcogenides (TMDCs), transition metal carbides (MXenes), graphene-derived 2D layered nanomaterials, phosphorene, and hexagonal boron nitride. Advanced synthesis methods and characterization instruments enabled an effective application for improved electrocatalytic water splitting and sustainable hydrogen production.

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Utilizing alternative energy sources to fossil fuels has remained a significant issue for humanity. In this context, efficient earth-abundant bifunctional catalysts for water splitting and energy storage technologies like hybrid supercapacitors have become essential for achieving a sustainable future. Herein, CoCr-LDH@VNiS was synthesized by hydrothermal synthesis.

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Two-dimensional (2D) transition metal dichalcogenide (TMDC) heterostructure is a new age strategy to achieve high electrocatalytic activity and ion storage capacity. The less complex and cost-effective applicability of the large-area TMDC heterostructure (HS) for energy applications require more research. Herein, we report the MoSe@WSe nanohybrid HS electrocatalyst prepared using liquid exfoliated nanocrystals, followed by direct electrophoretic deposition (EPD).

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Efficient hydrogen evolution by electrolysis plays an indispensable role for hydrogen fuel generation in green energy devices. In order to implement high-performance electrocatalytic activity, it is usually necessary to design economically viable, effective and stable electrocatalysts to reduce activation potential barriers. Herein, we report the photosensitive Ni-WSnanohybrids for enhanced electrocatalytic hydrogen evolution reaction (HER).

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The paper-based photodetector has recently captivated a great deal of attention in various opto-electronics applications because of facile, cost effective and green synthesis. Two-dimensional transition metal dichalcogenides materials are promising for photodetection under the broad spectral range. In this work, we have fabricated paper-based device by rubbing the tungsten di-selenide (WSe) crystals on paper substrate.

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Flexible photodetectors functionalized by transition metal dichalcogenides have attracted great attention due to their excellent photo-harvesting efficiency. However, the field of optoelectronics still requires advancement in the production of large-area, broad band and flexible photodetectors. Here we report a flexible, stable, broad band and fast photodetector based on a MoS/WSeheterostructure on ordinary photocopy paper with pencil-drawn graphite electrodes.

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forms persistent infections through the formation of biofilms that confer resistance to existing antifungal drugs. Biofilm targeting is therefore a promising strategy to combat infections. The WS/ZnO nanohybrids exhibits considerably improved antibiofilm activity and inhibited the biofilm formation by 91%, which is quite better than that for pristine WS, which is only 74%.

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The advancement of portable and flexible electronics that is integrated with multiple sensing functions has increasingly drawn considerable interest. The fabricated sensors would have the ability to sense multiple deformations like pressing, twisting and trivial vibrations such as pulses of wrist vibrations to mimic human skin. Presently, we implemented an easy, cost-effective and optimized fabrication technique for production of pressure sensors based on MoSe nanosheets coated on cellulose paper.

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High-performance electronics demand extremely sensitive piezo-resistive sensors with important features such as low-fabrication cost, easy implementation, low power consumption and high-pressure sensitivity over broad pressure range. Herein, we report a flexible piezo-resistive paper-based device functionalised by WSe nanosheets. An efficient and low-cost fabrication strategy using Whatman filter paper and tissue paper is adopted for versatile sensing applications.

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Recent research and development is focused in an intensive manner to increase the efficiency of solar energy conversion into electrical energy via photovoltaics and photo-electrochemical reactions. Electrocatalytic and photocatalytic water splitting into hydrogen and oxygen is a promising and emerging technology. Heterogeneous nanostructures based on semiconductor materials have attracted much attention to be used as catalysts, co-catalysts, photocatalysts and photoabsorbers.

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