Bis(μ-4,6-dimethyl-pyrimidine-2-thiol-ato)-κ(3) N,S:S;κ(3) S:N,S-bis-[(triphenyl-phosphane-κP)silver(I)].

The dinuclear title complex, [Ag2(C6H7N2S)2(C18H15P)2], comprises two inversion-related [Ag(C6H7N2S)(C18H15P)] units. The pyrimidine-thiol-ate anion acts both as a bridging and a chelating ligand. The Ag(I) ions are linked via two μ2-S donor atoms, which generate a strictly planar Ag2S2 core with an Ag⋯Ag separation of 2.