Self-diffusion of carbon dioxide in samaria/alumina aerogel catalyst using high field NMR diffusometry.

Pulsed field gradient (PFG) NMR was used to investigate the self-diffusion of carbon dioxide in alumina stabilized samaria aerogel catalyst, a promising porous catalyst for gas-phase reactions featuring high porosity and high surface area. For diffusion studies, the catalyst was prepared in two sample packing types, macroscopic monoliths (i.e.