In this study, an efficient hierarchical Co-Pi cluster/FeO nanorod/fluorine-doped tin oxide (FTO) micropillar three-dimensional (3D) branched photoanode was designed for enhanced photoelectrochemical performance. A periodic array of FTO micropillars, which acts as a highly conductive "host" framework for uniform light scattering and provides an extremely enlarged active area, was fabricated by direct printing and mist-chemical vapor deposition (CVD). FeO nanorods that act as light absorber "guest" materials and Co-Pi clusters that give rise to random light scattering were synthesized via a hydrothermal reaction and photoassisted electrodeposition, respectively.
View Article and Find Full Text PDFIn this study, a different number of indium zinc oxide (IZO) interlayers are fabricated into AlO-based transparent resistive switching memory on a transparent indium tin oxide (ITO)/glass substrate at room temperature. AlO/IZO multilayer transparent memory has a transmittance of at least 65% in the wavelength range of 400-900 nm. In addition, the AlO/IZO multilayer transparent memory can achieve an electroforming voltage that is 35.
View Article and Find Full Text PDFThermoelectrics operating at high temperature can cost-effectively convert waste heat and compete with other zero-carbon technologies. Among different high-temperature thermoelectrics materials, silicon nanowires possess the combined attributes of cost effectiveness and mature manufacturing infrastructures. Despite significant breakthroughs in silicon nanowires based thermoelectrics for waste heat conversion, the figure of merit (ZT) or operating temperature has remained low.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2021
Passive daytime radiative cooling, which is a process that removes excess heat to cold space as an infinite heat sink, is an emerging technology for applications that require thermal control. Among the different structures of radiative coolers, multilayer- and photonic-structured radiative coolers that are composed of inorganic layers still need to be simple to fabricate. Herein, we describe the fabrication of a nanoparticle-mixture-based radiative cooler that exhibits highly selective infrared emission and low solar absorption.
View Article and Find Full Text PDFIn this study, a high-performance photoanode based on 3D periodic, micropillar-structured fluorine-doped tin oxide (FTO-MP) deposited with BiVO is fabricated using the patterned FTO by direct printing and spray pyrolysis, followed by the deposition of BiVO by sputtering and V ion heat-treatment on the patterned FTO. The FTO-MP enables light scattering owing to its 3D periodic structure and increases the light absorption efficiency. In addition, the high electron mobility of FTO and enlarged surface area of FTO-MP enhance the separation efficiency.
View Article and Find Full Text PDFAnti-reflection technology is a core technology in the field of optoelectronic devices that is used to increase efficiency by reducing reflectance. In particular, the bio-mimetic moth-eye pattern has the advantage of being independent of wavelength, polarization, and angle of incidence. In this study, we fabricated a 1.
View Article and Find Full Text PDFAmong many candidates for photoanode materials of photoelectrochemical (PEC) cell, nanostructured tungsten trioxide (WO) is regarded as one of the most promising materials due to its superior electrical properties and adequate bandgap (∼2.8 eV) and band edge position. WO nanoflakes (WO NFs), which have merits on its high surface area and crystallinity, have been actively studied for this manner but solar-to-hydrogen efficiency of WO NFs based photoanode is still not sufficient both in light absorption and charge separation.
View Article and Find Full Text PDFA phosphor substrate converts a moderate amount of blue light to green light to produce white light. In this study, we have successfully demonstrated the enhancement of the light extraction efficiency of YAG:Ce phosphor substrate using a simple imprint process. Spin-on-glass materials were used to fabricate a pattern on the surface of a phosphor substrate, and nano- and micro-scale patterns were formed to test the performance according to the size of pattern.
View Article and Find Full Text PDFZnO-based hierarchical structures including nanoparticles (NPs), nanorods (NRs) and nanoflowers (NFs) on a 3D-printed backbone were effectively fabricated via the combination of the fused deposition modelling (FDM) 3D-printing technique and hydrothermal reaction. The photocatalytic performance of the ZnO-based hierarchical structures on the 3D-backbone was verified via the degradation of the organic pollutant methylene blue, which was monitored by UV-vis spectroscopy. The new photocatalytic architectures used in this investigation give an effective approach and wide applicability to overcome the limitation of photocatalysts such as secondary removal photocatalyst processes.
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