Noncoordinating Anions as Key Modulators of Supramolecular Structures, Optical and Electrical Properties in Nickel(II) Complexes.

This study explores the synthesis, structural characterization, and examination of two nickel(II) complexes, [Ni( )](NO) (complex ) and [Ni( )](ClO) (complex ), using the newly synthesized organic heterocyclic chelating ligand [4-imidazole-2,6-di(pyrazinyl)pyridine]. Through single-crystal X-ray diffraction, we have detailed the crystal structures of these complexes, highlighting their distorted octahedral geometries and diverse supramolecular interactions including π···π stacking, anion···π, and hydrogen bonding. These interactions crucially influence the formation of distinct one- and two-dimensional supramolecular architectures.

Deciphering Electrocatalytic Hydrogen Production in Water Through a Bioinspired Water-Stable Copper(II) Complex Adorned with (NS)-Donor Sites.

Electrocatalytic hydrogen production stands as a pivotal cornerstone in ushering the revolutionary era of the hydrogen economy. With a keen focus on emulating the significance of hydrogenase-like active sites in sustainable H generation, a meticulously designed and water-stable copper(II) complex, [Cl-Cu-L]ClO, featuring the N,S-type ligand, L (2,2'-((butane-2,3-diylbis(sulfanediyl))bis(methylene))dipyridine), has been crafted and assessed for its prowess in electrocatalytic H production in water, leveraging acetic acid as a proton source. The molecular catalyst, adopting a square pyramidal coordination geometry, undergoes -Cl substitution by HO during electrochemical conditions yielding [HO-Cu-L] as the true catalyst, showcases outstanding activity in electrochemical proton reduction in acidic water, achieving an impressive rate of 241.

Light-Induced Antiferromagnetic to Ferromagnetic Transition in Halogen Substituted 1,4-Bis(imidazolyl)benzene Systems: An Effect of Spin-Orbit Coupling and π-Stacking in Enhanced Photomagnetism.

Employing the spin-orbit coupling effect by introducing halogen substituents is an excellent strategy to tune the magnetic behavior of organic or metal-organic materials. Light is an alternative tool to modulate the magnetic behavior of a material through a photoinduced electron transfer process, without changing its chemical identity. In this work, three halogen containing 1,4-bis(4,5-diphenyl-1-imidazol-2-yl)benzene (F-BDPI, Cl-BDPI and Br-BDPI) systems have been chosen to exploit the role of halogen substituents on solid-state photoinduced phenomena.

Decrypting the hydrogen evolution in alkaline water with novel magnetoactive cobalt(II) complex-driven cobalt oxide electrocatalysts.

Under the gravity of future socio-economic development, the viability of water electrolysis still hinges on the accessibility of stable earth-abundant electrocatalysts and net energy efficiency. This work emphasizes the design and synthesis of two newly developed cobalt(II) complexes, [Co(HL)(NCS)] (Comono) and [Co(L)(CHOH)]ClO (Codi), with a (N,O)-donor ligand, HL (2-methoxy-6-(((2-methoxyphenyl)imino)methyl)phenol). The study delves into understanding their structural, morphological, magnetic, and charge transport characteristics.

Estuarine mangrove niches select cultivable heterotrophic diazotrophs with diverse metabolic potentials-a prospective cross-dialog for functional diazotrophy.

Introduction: Biological nitrogen fixation (BNF), an unparalleled metabolic novelty among living microorganisms on earth, globally contributes ~88-101 Tg N year to natural ecosystems, ~56% sourced from symbiotic BNF while ~22-45% derived from free-living nitrogen fixers (FLNF). The success of symbiotic BNF is largely dependent on its interaction with host-plant, however ubiquitous environmental heterotrophic FLNFs face many limitations in their immediate ecological niches to sustain unhindered BNF. The autotrophic FLNFs like cyanobacteria and oceanic heterotrophic diazotrophs have been well studied about their contrivances acclimated/adapted by these organisms to outwit the environmental constraints for functional diazotrophy.

Differentiating aliphatic and aromatic alcohols using triazine-based supramolecular organogelators: end group-specific selective gelation with chain length of alcohols.

Supramolecular gels have an extensive range of potential applications, out of which stimuli-responsive materials are a topic of contemporary research. Gels being kinetically entrapped materials can be tuned to different forms using external chemical stimuli. In this context, three different triazine gelators, each containing a unique end group, were examined for gelation in various solvent systems.

AIE active fluorescent organic nanoparticles based optical detection of Cu ions in pure water: a case of aggregation-disaggregation reversibility.

An AIE-active pyrene-terpyridine derivative, (4'-(pyren-1-yl)-2,2':6',2''-terpyridine) (1) was found to form nanoaggregate in an aqueous medium. The probe involved hydrogen bonding with solvent molecules that modulated the charge transfer behavior and consequently resulted in different spectroscopic behavior due to the formation of fluorescent organic nanoparticles (FONs). In the presence of Cu ions, FONs displayed a ratiometric red shift of the absorption band (360 to 420 nm) accompanied by a prominent naked-eye color change from colorless to light yellow.

Antioxidant enzyme activity and pathophysiological consequences in the sludge worm Tubifex tubifex under acute and sub-lethal exposures to the fungicide Tilt ®.

This study aimed to evaluate the effects of propiconazole on the tubificid segmented worm, Tubifex tubifex. The animals were exposed to various concentrations of propiconazole for 96 h to assess the acute effect of this fungicide and for subacute level animals were exposed for 14 days with 10% and 20% of the 96 h LC value (0.211 and 0.

Simultaneous above-knee amputation and ipsilateral total hip arthroplasty in a neglected neck of femur fracture with an insensate limb.

Total hip arthroplasty (THA) in patients with ipsilateral mid-thigh amputation is surgically challenging. We report a case of same setting THA and ipsilateral above-knee amputation in a male patient. The patient had 8 months old neglected neck femur fracture and ipsilateral femur shaft fracture with 14 cm bone loss.

Comparative Study of Nitro- and Azide-Functionalized Zn -Based Coordination Polymers (CPs) as Fluorescent Turn-On Probes for Rapid and Selective Detection of H S in Living Cells.

Selective detection of H S in the cellular systems using fluorescent CPs/MOFs is of great scientific interest due to their outstanding aqueous stability, biocompatibility and real-time detection ability. Fabrication of such materials using complete biologically essential elements and applying them as an efficient biosensor is still quite challenging. In this context, two newly synthesized CPs containing biologically essential metal ion (Zn) and nitro/azido functional groups into the framework to sense extracellular and intracellular H S by reducing into respective amines are presented.

Metal-organic frameworks as proton conductors: strategies for improved proton conductivity.

Recent studies on proton conductivity using pristine MOFs and their composite materials have established an outstanding area of research owing to their potential applications for the development of high performance solid state proton conductors (SSPCs) and proton exchange membranes (PEMs) in fuel cells (FCs). MOFs, as crystalline organic and inorganic hybrid materials, provide a large number of degrees of freedom in their framework composition, coordination environment, and chemically functionalized pores for the targeted design of improved proton carriers, functioning over a wide range of temperature and humidity conditions. Herein, our efforts have been emphasized on fundamental principles and different design strategies to achieve enhanced proton conductivity with appropriate examples.

Thermocatalytic hydrogen peroxide generation and environmental disinfection by BiTe nanoplates.

The highly reactive nature of reactive oxygen species (ROS) is the basis for widespread use in environmental and health-related fields. Conventionally, there are only two kinds of catalysts used for ROS generation: photocatalysts and piezocatalysts. However, their usage has been limited due to various environmental and physical factors.

Electrowetting-on-dielectric (EWOD): Current perspectives and applications in ensuring food safety.

Digital microfluidic (DMF) platforms have contributed immensely to the development of multifunctional lab-on-chip systems for performing complete sets of biological and analytical assays. Electrowetting-on-dielectric (EWOD) technology, due to its outstanding flexibility and integrability, has emerged as a promising candidate for such lab-on-chip applications. Triggered by an electrical stimulus, EWOD devices allow precise manipulation of single droplets along the designed electrode arrays without employing external pumps and valves, thereby enhancing the miniaturization and portability of the system towards transcending important laboratory assays in resource-limited settings.

Lewis acid catalyzed reactivity switch: pseudo three-component annulation of nitrosoarenes and (epoxy)styrenes.

A Lewis acid catalyzed annulation reaction via arene functionalization of nitrosoarenes and C-C cleavage of (epoxy)styrene to provide arylquinolines is reported. The Lewis acid catalyst altered the annulation pattern providing arylquinolines instead of oxazolidines. The reaction with styrene resulted in a mixture of 2,4-diarylquinoline and 4-arylquinoline, while only 3-arylquinoline was formed from the reaction of epoxystyrene.

TiO-Templated BaTiO Nanorod as a Piezocatalyst for Generating Wireless Cellular Stress.

Although the piezoelectric property of a BaTiO nanoparticle is routinely used in energy harvesting application, it can also be exploited for wireless cell stimulation and cell therapy. However, such biomedical application is rare due to limited availability of colloidal BaTiO nanoparticles of <100 nm hydrodynamic size with good piezocatalytic property and efficient biolabeling performance. Here, we report a colloidal form of a piezocatalytic BaTiO-based nanorod of <100 nm hydrodynamic size that can offer wireless cell stimulation.

Recent advancements in solid-liquid triboelectric nanogenerators for energy harvesting and self-powered applications.

The abundance of water on earth provides a large window to utilize the mechanical energy within river currents and ocean waves. In this regard, hydropower harvesting through solid-liquid contact electrification has received considerable interest in the recent past. Despite advancements in nanotechnology, liquid energy harvesting devices, especially solid-liquid triboelectric nanogenerators (S-L TENGs), require efficient engineering of the interfacial properties of their substrates to transfer liquid mass and momentum rapidly with the effective generation/transfer of surface charges.

Diastereoselective and Reversed Regioselective Annulations of -Alkyl Anilines to Julolidines and Lilolidines.

A three-component annulation reaction of -alkyl anilines, cyclic 1,3-dicarbonyl compounds, and aryl aldehydes to julolidines and lilolidines is reported. The 6π-electrocyclization enabled the annulation to proceed with reversed regioselectivity as compared with the annulation that occurs in the Povarov reaction. Both cyclic and acyclic -alkyl anilines participated in the reaction to provide a wide range of julolidines and lilolidines as the single regio- and diastereoisomers in good to excellent yields.

Blue Emitting BaAlO:Ce Nanophosphors with High Color Purity and Brightness for White LEDs.

In this work, strongly blue emitting Ce3+-activated BaAl2O4 nanophosphors were successfully synthesized by a sol-gel technique. The crystal structure, morphology, and microstructure of the nanophosphors have been studied by X-ray powder diffraction, field emission scanning electron microscopy, and high-resolution transmission electron microscopy. The photoluminescence spectra show the impact of concentration variation of Ce3+ on the photoluminescence emission of the phosphor.

Enhanced Photoluminescence Properties of Low-Dimensional Eu-Activated YAlO Phosphor Compared to Bulk for Solid-State Lighting Applications and Latent Fingerprint Detection-Based Forensic Applications.

In recent years, nanoscale phosphors have become vital in optoelectronic applications and to understand the improved performance of nanophosphors over bulk material, detailed investigation is essential. Herein, trivalent europium-activated Y4Al2O9 phosphors were developed by solid-state reaction and solvothermal reaction methods and their performance as a function of their dimension was studied for various applications. Under 394 nm optical excitation, the photoluminescence (PL) emission, excited state lifetime of the nanophosphor, exhibits greater performance than its bulk counterpart.

Resonant energy transfer in a van der Waals stacked MoS - functionalized graphene quantum dot composite with ab initio validation.

Graphene-based van der Waals (vdW) heterostructures can facilitate exciting charge transfer dynamics in between structural layers with the emission of excitonic quasi-particles. However, the chemical formation of such heterostructures has been elusive thus far. In this work, a simple chemical approach is described to form such van der Waals (vdW) heterostructures using few layer MoS2 sheet embedded quantum dots (QDs) and amine-functionalized graphene quantum dots (GQDs) to probe the energy transfer mechanism for tunable photoluminescence (PL).

White light emitting MgAlO:Dy,Eu nanophosphor for multifunctional applications.

Feeble white emission with a low Colour Rendering Index (CRI) has become the principal gridlock for the extensive commercialization of phosphor converted white LEDs (pc-WLEDs). Fusion of red, green and blue emitting rare-earth (RE) ions in a suitable host can overcome these drawbacks but the energy migration between multiple RE ions at single excitation wavelength defines the key standpoint in designing such white light emitting phosphors. Apart from the abovementioned obstacles, recently traditional optical temperature sensors based on RE ions have faced difficulties due to their low relative sensitivity and large detection error.

Neutralizing the Charge Imbalance Problem in Eu-Activated BaAlO Nanophosphors: Theoretical Insights and Experimental Validation Considering K Codoping.

In recent years, rare-earth-doped nanophosphors have attracted great attention in the field of luminescent materials for advanced solid-state lighting and high-resolution display applications. However, the low efficiency of concurrent red phosphors creates a major bottleneck for easy commercialization of these devices. In this work, intense red-light-emitting K-codoped BaAlO:Eu nanophosphors having an average crystallite size of 54 nm were synthesized via a modified sol-gel method.