We apply periodic control to realize a quantum thermal transistor, which we term as the Floquet quantum thermal transistor. Periodic modulation allows us to control the heat flows and achieve large amplification factors even for fixed bath temperatures. Importantly, this transistor effect persists in the cutoff region, where traditional quantum thermal transistors operating in the absence of periodic modulation, fail to act as viable heat modulation devices.
View Article and Find Full Text PDFWe map spatially correlated electrical current on the stacking boundaries of pristine and doped hexagonal boron nitride (hBN) to distinguish from its insulating bulk conductive atomic force microscopy (CAFM). While the pristine edges of hBN show an insulating nature, the O-doped edges reveal a current 2 orders of higher even for bulk layers where the direct transmission through tunnel barrier is implausible. Instead, the nonlinear current-voltage characteristics (-) at the edges of O-doped hBN can be explained by trap-assisted lowering of the tunnel barrier by adopting a Poole-Frenkel (PF) model.
View Article and Find Full Text PDFThe supramolecular hydrogel of a simple organic salt derived from a primary amine and a mono-sulfonic acid displayed a proton conductivity of 1.2 × 10 S cm. The hitherto unknown example of the supramolecular gel displaying proton conductivity provides an intriguing alternative to liquid electrolyte or polymer gel electrolytes.
View Article and Find Full Text PDFWe experimentally investigate the electronic transport through a double-wall carbon nanotube filled with Fe nanoparticles. At very low temperatures, the Kondo effect is observed between the confined electrons in the nanotube quantum dot and the delocalized electrons in the leads connecting the nanotube. We demonstrate that the presence of magnetic nanoparticles in the inner core of the nanotube results in a hysteretic behavior of the differential resistance of the system when the magnetic field is varied.
View Article and Find Full Text PDFCoupling spins of molecular magnets to two-dimensional (2D) materials provides a framework to manipulate the magneto-conductance of 2D materials. However, with most molecules, the spin coupling is usually weak and devices fabricated from these require operation at low temperatures, which prevents practical applications. Here, we demonstrate field-effect transistors based on the coupling of a magnetic molecule quinoidal dithienyl perylenequinodimethane (QDTP) to 2D materials.
View Article and Find Full Text PDFThe coordination chemistry between copper acetate [Cu2(OAc)4] and 5,10,15,20-tetra-4-pyridyl-21H,23H-porphine (porphyrin, H2TPyP) is found to give rise to either a 2D metal-organic framework (MOF) [Cu(TPyP)Cu2(O2CCH3)4] or a 3D MOF [Cu(TPyP)CuCl2]·2.5TCE·7H2O], depending on the choice of solvent. The 2D MOF can be made into a film, which was doped with 7,7,8,8-tetracyanoquinodimethane (TCNQ), and the electrical conductivity of the thin film was increased by 3 orders of magnitude with respect to that of the undoped Cu-MOF.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
December 2007
Nanocrystalline Au(x)Cu(1-x) films were synthesized by depositing Cu/Au/Cu multilayer in nanocrystalline thin film form with requisite thickness of individual layers onto fused silica substrates by high pressure sputtering technique. The absorbance spectra showed only one surface plasmon peak for all the compositions with the exception that the peak position did not indicate gradual shift as gold concentration was increased. Peak position for the two compositions corresponding to the two superlattice structures, AuCu3 and AuCu, deviated significantly from linear variation.
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