Waste-Wood-Isolated Cellulose-Based Activated Carbon Paper Electrodes with Graphene Nanoplatelets for Flexible Supercapacitors.

Waste wood, which has a large amount of cellulose fibers, should be transformed into useful materials for addressing environmental and resource problems. Thus, this study analyzed the application of waste wood as supercapacitor electrode material. First, cellulose fibers were extracted from waste wood and mixed with different contents of graphene nanoplatelets (GnPs) in water.

Homogeneous Elongation of N-Doped CNTs over Nano-Fibrillated Hollow-Carbon-Nanofiber: Mass and Charge Balance in Asymmetric Supercapacitors Is No Longer Problematic.

The hurdle of fabricating asymmetric supercapacitor (ASC) devices using a faradic cathode and a double layer anode is challenging due to the required large amount of active mass of anodic material compared to that of the cathodic material during mass balancing due to the large difference in capacitance values of the two electrodes. Here, the problem is addressed by engineering a negative electrode that furnishes an ultrahigh capacitance. An in situ developed metal-organic framework (MOF)-based thermal treatment is adopted to grow highly porous N-doped carbon nanotubes (CNTs) containing submerged Co nanoparticles over nano-fibrillated electrospun hollow carbon nanofibers (HCNFs).

Polypyrrole Nanotunnels with Luminal and Abluminal Layered Double Hydroxide Nanosheets Grown on a Carbon Cloth for Energy Storage Applications.

The structural design of transition metal-based electrode materials with gigantic energy storage capabilities is a crucial task. In this work, we report an assembly of thin layered double hydroxide (LDH) nanosheets arrayed throughout the luminal and abluminal parts of polypyrrole tunnels fastened onto both sides of a carbon cloth as a battery-type energy storage system. Electron microscopy images reveal that the resulting electrode (NiCo-LDH@H-PPy@CC, where H-PPy@CC represents carbon cloth-supported hollow polypyrrole fibers) is constructed by combining luminal and abluminal NiCo-LDH nanosheets onto a long polypyrrole tunnel on a carbon cloth.

Highly ordered nanoarrays catalysts embedded in carbon nanotubes as highly efficient and robust air electrode for flexible solid-state rechargeable zinc-air batteries.

The development of multicomponent materials is the most efficient and successful way for creating advanced multifunctional catalysts. Herein, the bimetal FeCo nanoarrays enclosed N-CNTs have a high surface on carbon cloth support, which promotes efficient electron transport and prevents nanoparticle aggregation. Taking advantage of the high-level use of active material and fast charge transfer, the developed electrocatalyst exhibits excellent multifunctional electrocatalyst such as oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER).

Integrating the Essence of a Metal-Organic Framework with Electrospinning: A New Approach for Making a Metal Nanoparticle Confined N-Doped Carbon Nanotubes/Porous Carbon Nanofibrous Membrane for Energy Storage and Conversion.

The fabrication of an economic and efficient multifunctional advanced nanomaterial with a rational composition and configuration by a facile methodology is a crucial challenge. Herein, we are the first to report the growth of Co nanoparticle-integrated nitrogen-doped carbon nanotubes (N-CNTs) on porous carbon nanofibers by simply heating in the situ-developed metal-organic framework (MOF)-based electrospun nanofibrous membrane with no need for an external supply of any additional precursors and reducing gases. The long and entangled N-CNTs originating from highly porous and graphitic carbon nanofibers offer good flexibility, large surface area, high porosity, high conductivity, the homogeneous incorporation of heteroatoms and metallic constituents, and an abundant exposure of active nanocatalytic sites.

White-light-emitting triphasic fibers as a phosphor for light-emitting diodes.

White-light-emitting materials have received significant attention because of their potential application in lighting, displays, and sensors. However, it is a challenge to obtain white light from one phosphor, because the basic requirement of the white light emission spectrum is that it should be wide enough to cover the entire visible light region. In this study, we have designed and demonstrated a white-light-emitting PMMA-CBS-127/PVP-coumarin 6/PAN-rhodamine B (PSCR) fibrous membrane, which was prepared through a triphasic electrospinning method.

Phytic acid controlled synthesis of amorphous cobalt phosphate/carbon composite as anode materials with a high mass loading for symmetrical supercapacitor: amorphization of the electrode to boost the energy density.

Transition metal phosphate (TMPi)-based composites as anode electrode materials in supercapacitor applications are less reported. Herein, we report a phytic acid (PA)-assisted in situ-formed amorphous cobalt phosphate/carbon (CoPi/C) composite grown on a flexible woven carbon cloth (CC) a simple one-step carbonization approach. The tunable synthesis of amorphous and crystalline composites is shown by simply controlling the concentration of the cobalt salts.

Three-dimensional porous carbonaceous network with in-situ entrapped metallic cobalt for supercapacitor application.

Herein, we outline the fabrication of highly porous three-dimensional carbon-fiber network anchored with uniform metallic cobalt (Co) via electrospinning and subsequent post-modification approaches. First, cobalt acetate solution saturated electrospun polyacrylonitrile (PAN) nanofibrous mat was subjected to sodium borohydride (NaBH) solution which results in the fabrication of three dimensional (3D) hierarchical multilayer network. Restructuring of the 2D mat into multilayered sponges with metal particles entrapment is attributed to the in-situ generated hydrogen gas into the interconnected pores of the fibrous network simultaneous with reduction of cobalt salt into metallic cobalt by NaBH.

Synthesis of Carbon Foam from Waste Artificial Marble Powder and Carboxymethyl Cellulose via Electron Beam Irradiation and Its Characterization.

Carbon foams were prepared by carbonization of carboxymethyl cellulose (CMC)/waste artificial marble powder (WAMP) composites obtained via electron beam irradiation (EBI); these composites were prepared by mixing eco-friendly CMC with WAMP as the fillers for improved their poor mechanical strength. Gel fractions of the CMC/WAMP composites obtained at various EBI doses were investigated, and it was found that the CMC/WAMP composites obtained at an EBI dose of 80 kGy showed the highest gel fraction (95%); hence, the composite prepared at this dose was selected for preparing the carbon foam. The thermogravimetric analysis of the CMC/WAMP composites obtained at 80 kGy; showed that the addition of WAMP increased the thermal stability and carbon residues of the CMC/WAMP composites at 900 °C.

Graphene-Carbon-Metal Composite Film for a Flexible Heat Sink.

The heat generated from electronic devices such as light emitting diodes (LEDs), batteries, and highly integrated transistors is one of the major causes obstructing the improvement of their performance and reliability. Herein, we report a comprehensive method to dissipate the generated heat to a vast area by using the new type of graphene-carbon-metal composite film as a heat sink. The unique porous graphene-carbon-metal composite film that consists of an electrospun carbon nanofiber with arc-graphene (Arc-G) fillers and an electrochemically deposited copper (Cu) layer showed not only high electrical and thermal conductivity but also high mechanical stability.