Influence of Zirconium on the Microstructure, Selected Mechanical Properties, and Corrosion Resistance of TiTaNb(HfMo)Zr High-Entropy Alloys.

The presented work considers the influence of the hafnium and molybdenum to zirconium ratio of TiTaNb(HfMo)Zr (where x = 0, 5, 10, 15, 20 at.%) high-entropy alloys in an as-cast state for potential biomedical applications. The current research continues with our previous results of hafnium's and molybdenum's influence on a similar chemical composition.

Influence of Hafnium Addition on the Microstructure, Microhardness and Corrosion Resistance of TiTaNb(ZrMo)Hf (where x = 0, 5, 10, 15 and 20 at.%) High Entropy Alloys.

The presented work aimed to investigate the influence of the hafnium/(zirconium and molybdenum) ratio on the microstructure, microhardness and corrosion resistance of TiTaNb(ZrMo)Hf (where x = 0, 5, 10, 15 and 20 at.%) high entropy alloys in an as-cast state produced from elemental powder and obtained via the vacuum arc melting technique. All studied alloys contained only biocompatible elements and were chosen based on the thermodynamical calculations of phase formation predictions after solidification.

Interfacial Polarization Phenomena in Compressed Nanowires of SbSI.

The systematic studies of the extrinsic Maxwell-Wagner-Sillars polarization process in compressed antimony sulfoiodide (SbSI) nanowires are carried out by dielectric spectroscopy. The dielectric response is studied in temperature (100≤T≤350) K and frequency (10-3≤f≤106) Hz ranges. Dielectric functions commonly used for the analysis of dielectric spectra related to intrinsic polarization processes were applied in the elaboration of experimental data.

Influence of Molybdenum on the Microstructure, Mechanical Properties and Corrosion Resistance of TiTaNb(ZrHf)Mo (Where: x = 0, 5, 10, 15, 20) High Entropy Alloys.

The presented work was focused on investigating the influence of the (hafnium and zirconium)/molybdenum ratio on the microstructure and properties of TiTaNb(ZrHf)Mo (where: x = 0, 5, 10, 15, 20 at.%) high entropy alloys in an as-cast state. The designed chemical composition was chosen due to possible future biomedical applications.

Fast and Efficient Piezo/Photocatalytic Removal of Methyl Orange Using SbSI Nanowires.

Piezocatalysis is a novel method that can be applied for degradation of organic pollutants in wastewater. In this paper, ferroelectric nanowires of antimony sulfoiodide (SbSI) have been fabricated using a sonochemical method. Methyl orange (MO) was chosen as a typical pollutant, as it is widely used as a dye in industry.

Effect of Nanoparticles Surface Charge on the (L.) Roots Development and Their Movement into the Root Cells and Protoplasts.

Increasing usage of gold nanoparticles (AuNPs) in different industrial areas inevitably leads to their release into the environment. Thus, living organisms, including plants, may be exposed to a direct contact with nanoparticles (NPs). Despite the growing amount of research on this topic, our knowledge about NPs uptake by plants and their influence on different developmental processes is still insufficient.

A Ferroelectric-Photovoltaic Effect in SbSI Nanowires.

A ferroelectric-photovoltaic effect in nanowires of antimony sulfoiodide (SbSI) is presented for the first time. Sonochemically prepared SbSI nanowires have been characterized using high-resolution transmission electron microscopy (HRTEM) and optical diffuse reflection spectroscopy (DRS). The temperature dependences of electrical properties of the fabricated SbSI nanowires have been investigated too.

The development of a hairless phenotype in barley roots treated with gold nanoparticles is accompanied by changes in the symplasmic communication.

Uptake of water and nutrients by roots affects the ontogenesis of the whole plant. Nanoparticles, e.g.

Unique chromoplast organisation and carotenoid gene expression in carotenoid-rich carrot callus.

The new model orange callus line, similar to carrot root, was rich in carotenoids due to altered expression of some carotenogenesis-associated genes and possessed unique diversity of chromoplast ultrastructure. Callus induced from carrot root segments cultured in vitro is usually pale yellow (p-y) and poor in carotenoids. A unique, non-engineered callus line of dark orange (d-o) colour was developed in this work.

Ferroelectric SbSI nanowires for ammonia detection at a low temperature.

For the first-time, an ammonia (NH) gas sensor has been fabricated using antimony sulfoiodide (SbSI). A few aligned SbSI nanowires have been bonded to Au microelectrodes on a glass substrate. The fabricated sensor has been tested for various concentrations of NH in N at operating temperatures below (T = 280 K) and above (T = 304 K) Curie point of SbSI.

Using of sonochemically prepared SbSI for electrospun nanofibers.

A novel polymeric, polyacrylonitrile (PAN) nanofibers containing ferroelectric and semiconducting antimony sulfoiodide (SbSI) have been made by electrospinning. SbSI nanowires, used as the filler, have been prepared sonochemically from antimony sulphide (SbS) and antimony tri-iodide (SbI) for the first time. Nanocrystalline SbSI has been fabricated in ethanol under ultrasonic irradiation (20kHz, 565W/cm) at 323K within 2h.

Fate of neutral-charged gold nanoparticles in the roots of the Hordeum vulgare L. cultivar Karat.

Nanoparticles (NPs) have a significant impact on the environment and living organisms. The influence of NPs on plants is intensively studied and most of the data indicate that NPs can penetrate into plants. The studies presented here were performed on the roots of Hordeum vulgare L.

Sonochemical growth of nanomaterials in carbon nanotube.

Recent achievements in investigations of carbon nanotubes (CNTs) filled with ternary chalcohalides (antimony sulfoiodide (SbSI) and antimony selenoiodide (SbSeI)) are presented. Parameters of sonochemical encapsulation of nanocrystalline semiconducting ferroelectric SbSI-type materials in CNTs are reported. This low temperature technology is convenient, fast, efficient and environmentally friendly route for producing novel type of hybrid materials useful for nanodevices.

Sonochemical growth of antimony selenoiodide in multiwalled carbon nanotube.

This paper presents, for the first time, the nanocrystalline, semiconducting antimony selenoiodide (SbSeI) grown in multi-walled carbon nanotubes (CNTs). It was prepared sonochemically using elemental Sb, Se, and I in the presence of ethanol under ultrasonic irradiation (35 kHz, 2.6 W/cm2) at 323 K for 3 h.

TEM studies of plasma nitrided austenitic stainless steel.

Cross-sectional transmission electron microscopy and X-ray phase analysis were used to study the structure of a layer formed during nitriding the AISI 316L stainless steel at temperature 440 degrees C. It was found that the applied treatment led to the formation of 6-microm-thick layer of the S-phase. There is no evidence of CrN precipitation.

Using of sonochemically prepared components for vapor phase growing of SbI3.3S8.

The using of sonochemically prepared components for growth of SbI(3).3S(8) single crystals from the vapor phase is presented for the first time. The good optical quality of the obtained crystals is important because this material is valuable for optoelectronics due to its non-linear optical properties.

Sonochemical preparation of SbS(1-x)Se(x)I nanowires.

A sonochemical method for direct preparation of nanowires of SbS(1-x)Se(x)I solid solution has been established. The SbS(1-x)Se(x)I gel was synthesized using elemental Sb, S, Se and I in the presence of ethanol under ultrasonic irradiation (35kHz, 2W/cm(2)) at 50 degrees C for 2h. The product was characterized by using techniques such as powder X-ray diffraction, scanning electron microscopy, high-resolution transmission electron microscopy, energy dispersive X-ray analysis, selected area electron diffraction, and optical diffuse reflection spectroscopy.

Sonochemical preparation of antimony subiodide.

The substantiated isolation of the antimony subiodide (Sb(3)I) is presented for the first time. It has been prepared using elemental Sb and I in ethanol under ultrasonic irradiation at 323 K. Its composition was characterized using X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray analysis (EDAX).

Sonochemical growth of antimony sulfoiodide in multiwalled carbon nanotube.

This paper presents for the first time the nanocrystalline, semiconducting ferroelectrics antimony sulfoiodide (SbSI) grown in multiwalled carbon nanotubes (CNTs). It was prepared sonochemically using elemental Sb, S and I in the presence of methanol under ultrasonic irradiation (35kHz, 2.6W/cm(2)) at 323K for 3h.

Sonochemical preparation of SbSeI gel.

A novel sonochemical method for direct preparation of nanocrystalline antimony selenoiodide (SbSeI) has been established. The SbSeI gel was synthesized using elemental Sb, Se, and I in the presence of ethanol under ultrasonic irradiation (35 kHz, 2W/cm(2)) at 50 degrees C for 2h. The product was characterized by using techniques such as powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), and optical diffuse reflection spectroscopy (DRS).

Influence of the solvent on ultrasonically produced SbSI nanowires.

The influence of the substitution of methanol in place of ethanol during the ultrasonic production of antimony sulfoiodide (SbSI) nanowires is presented. The new technology is faster and more efficient at temperatures greater than 314 K. The products were characterized by using techniques such as powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), optical diffuse reflection spectroscopy (DRS) and IR spectroscopy.

Ferroelectric properties of ultrasonochemically prepared SbSI ethanogel.

This article presents for the first time the electrical properties of sonochemically synthesised, high-surface-area SbSI ethanogel made up of large quantity nanowires with lateral dimensions of about 10-50 nm and lengths reaching up to several micrometers. The composition, morphology, dimensions, microstructures, and optical energy gap of the new form of SbSI were characterized. This material is a semiconducting ferroelectric as in the case of bulk SbSI crystals.

On the structured imperfections of bulk GaSb using high resolution transmission electron microscopy.

GaSb is a promising III-V direct band gap semiconductor with sphalerite type FCC structure. Its band gap value has made it an excellent candidate for the conversion of infrared radiation to electricity. The wafers of GaSb, that were studied, originated from ingots grown with the Liquid Encapsulated Chochralski method.

Sonochemical preparation of SbSI gel.

A novel sonochemical method for direct preparation of nanocrystalline antimony sulfoiodide (SbSI) has been established. The SbSI gel was synthesized using elemental Sb, S and I in the presence of ethanol under ultrasonic irradiation (35 kHz, 2 W/cm2) at 50 degrees C for 2 h. The products were characterized by using techniques such as powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), and optical diffuse reflection spectroscopy (DRS).

Transmission electron microscopy analysis of phase separation in GaInAsSb films grown on GaSb substrate.

The GaSb-based quaternary alloys are a good choice for thermophotovoltaic applications. The thermophotovoltaic cell converts infrared radiation to electricity, using the same principles as photovoltaic devices. The aim of the present work was the microstructural study of such an alloy, namely Ga(0.