Unifying Atoms and Colloids near the Glass Transition through Bond-Order Topology.

In this combined experimental and simulation study, we utilize bond-order topology to quantitatively match particle volume fraction in mechanically uniformly compressed colloidal suspensions with temperature in atomistic simulations. The obtained mapping temperature is above the dynamical glass transition temperature, indicating that the colloidal systems examined are structurally most like simulated undercooled liquids. Furthermore, the structural mapping procedure offers a unifying framework for quantifying relaxation in arrested colloidal systems.

Chemiluminescent wood.

Wood materials incorporating new properties are of great interest, especially for advanced applications such as sustainable optics and photonics. In this work we describe a wood functionalization approach, comprising the incorporation of artificial chemiluminescent systems (phenyl oxalate ester‑hydrogen peroxide-fluorophore, and luminol-ferricyanide), resulting in light-emitting wood. By a detailed characterisation of the light emission features we point out the complex interaction between wood scaffold and chemiluminescent systems, especially the quenching effect of wood extractives (for the TCPO-HO-fluorophore system) and lignin (for the luminol-ferricyanide system).

The ratting of North America: A 350-year retrospective on species compositions and competition.

While the impacts of black () and brown () rats on human society are well documented-including the spread of disease, broad-scale environmental destruction, and billions spent annually on animal control-little is known about their ecology and behavior in urban areas due to the challenges of studying animals in city environments. We use isotopic and ZooMS analysis of archaeological (1550s-1900 CE) rat remains from eastern North America to provide a large-scale framework for species arrival, interspecific competition, and dietary ecology. Brown rats arrived earlier than expected and rapidly outcompeted black rats in coastal urban areas.

Trauma Patient-Centered Discharge Plan Form: A Pilot Study.

Background: Comprehensive and multidisciplinary discharge planning can improve trauma patient throughput, decrease length of hospitalization, increase family and patient support, and expedite hospital discharge.

Objective: This study aimed to assess the feasibility and acceptability of implementing a patient-centered discharge plan form for adult trauma patients.

Methods: A single-center pilot study was conducted with adult trauma patients on a neurosurgical medical-surgical floor at a Level II trauma center in the Western United States from January to February 2023.

Balancing anticoagulation and hemostasis in an infant with severe hemophilia A during cardiac transplantation: Review of the literature and development of a surgical protocol.

Hemophilia A is a disorder resulting in a deficiency of clotting factor VIII that can lead to life-threatening bleeding. Evidence-based guidelines for surgical interventions like cardiac surgery are limited. Anticoagulation is necessary for cardiac bypass, thus risk of bleeding in a patient with hemophilia is increased and requires careful attention to maintain hemostasis.

Reprocessable Polyurethane Foams Using Acetoacetyl-Formed Amides.

Like any other thermosetting material, polyurethane foams (PUFs) contain permanent cross-links that hinder their reprocessability and make their recyclability a tedious and environmentally unfriendly process. Herein, we introduce acetoacetyl-formed amides, formed by the reaction of isocyanates with acetoacetate groups, as dynamic units in the backbone of PUFs. By extensive variation of the foam composition, optimum parameters have been found to produce malleable foams above temperatures of 130 °C, without the requirement of any solvent during the foaming process.

Anisotropic wood-hydrogel composites: Extending mechanical properties of wood towards soft materials' applications.

Delignified wood (DW) offers a versatile platform for the manufacturing of composites, with material properties ranging from stiff to soft and flexible by preserving the preferential fiber directionality of natural wood through a structure-retaining production process. This study presents a facile method for fabricating anisotropic and mechanically tunable DW-hydrogel composites. These composites were produced by infiltrating delignified spruce wood with an aqueous gelatin solution followed by chemical crosslinking.

Time-domain Tollens reaction: synthesising silver nanoparticles with the formaldehyde clock.

The addition of silver(i) ions to the methylene glycol-sulphite (MGS) clock reaction results in the sudden formation of metallic silver nanoparticles. Stable suspensions are obtained in the presence of poly(vinylpyrrolidone). The time delay before the appearance of the particles, as well as their size, decreases with the initial methylene glycol concentration while their monodispersity increases.

The role of spatial information in an approximate cross-modal number matching task.

The approximate number system (ANS) is thought to be an innate cognitive system that allows humans to perceive numbers (>4) in a fuzzy manner. One assumption of the ANS is that numerosity is represented amodally due to a mechanism, which filters out nonnumerical information from stimulus material. However, some studies show that nonnumerical information (e.

Parent-child interaction during a home STEM activity and children's handwashing behaviors.

We examined correlations between a home-based STEM activity illustrating the importance of soap use during handwashing and children's (4-to 7-year-olds,  = 81, 42 girls, 39 boys) use of soap when washing their hands. Parents and children either participated in or watched the activity. Children reflected on the activity immediately afterward and a week later.

Domain Size Regulation in Phospholipid Model Membranes Using Oil Molecules and Hybrid Lipids.

The formation of domains in multicomponent lipid mixtures has been suggested to play a role in moderating signal transduction in cells. Understanding how domain size may be regulated by both hybrid lipid molecules and impurities is important for understanding real biological processes; at the same time, developing model systems where domain size can be regulated is crucial to enable systematic studies of domain formation kinetics and thermodynamics. Here, we perform a model study of the effects of oil molecules, which swell the bilayer, and line-active hybrid phospholipids using a thermally induced liquid-solid phase separation in planar, free-standing lipid bilayers consisting of DOPC and DPPC (1,2-dioleoyl--glycero-3-phosphocholine and 1,2-dipalmitoyl--glycero-3-phosphocholine, respectively).

Relations between children's exploration in a children's museum and their reflections about their exploration.

We examined 6- to 9-year-olds' (N = 60, 35 girls, 34% White, 23% Hispanic, 2% Black/African American, 2% Asian/Asian American, 22% Mixed Ethnicity/Race, 17% Unavailable, collected April-September 2019 in Providence, RI, USA) first-person perspectives on their exploration of museum exhibits. We coded goal setting, goal completion, and behaviors that reflected changes to how goals were accomplished. Whether children played collaboratively related to how often they revised behaviors to accomplish goals (OR = 2.

Natural Wood-Based Catalytic Membrane Microreactors for Continuous Hydrogen Generation.

The development of controlled processes for continuous hydrogen generation from solid-state storage chemicals such as ammonia borane is central to integrating renewable hydrogen into a clean energy mix. However, to date, most reported platforms operate in batch mode, posing a challenge for controllable hydrogen release, catalyst reusability, and large-scale operation. To address these issues, we developed flow-through wood-based catalytic microreactors, characterized by inherent natural oriented microchannels.

Hybrid sideways/longitudinal swimming in the monoflagellate : from aerotactic band to biofilm.

MR-1 are facultative aerobic electroactive bacteria with an appealing potential for sustainable energy production and bioremediation. They gather around air sources, forming aerotactic bands and biofilms. Here, we experimentally follow the evolution of the band around an air bubble, and we find good agreement with the numerical solutions of the pertinent transport equations.

Fluorescent supramolecular hierarchical self-assemblies from glycosylated 4-amino- and 4-bromo-1,8-naphthalimides.

An investigation into the self-assembly of two 4-amino- and a 4-bromo-1,8-naphthalimide (Nap) based structures (1-3) possessing an appended glycan unit, from protic polar media, is presented. The results demonstrate the formation of complex hierarchical luminescent aggregates, wherein the morphologies, sizes and spherical structures were highly dependent on both the media and the Nap structure. Upon cleaving the native glycosidic bond, using an enzyme, the structure/morphology of the self-assembly of 3 in buffered solution was significantly transformed.

Light-Responsive Arylazopyrazole Gelators: From Organic to Aqueous Media and from Supramolecular to Dynamic Covalent Chemistry.

Versatile photoresponsive gels based on tripodal low molecular weight gelators (LMWGs) are reported. A cyclohexane-1,3,5-tricarboxamide (CTA) core provides face-to-face hydrogen bonding and a planar conformation, inducing the self-assembly of supramolecular polymers. The CTA core was substituted with three arylazopyrazole (AAP) arms.

Stability analysis for a thermodynamically consistent model of relativistic fluid dynamics.

In relativistic fluid mechanics, positive entropy production is known to be insufficient for guaranteeing stability. Much stronger criteria for thermodynamic admissibility have become available in nonequilibrium thermodynamics. We here perform a linear stability analysis for a model of relativistic hydrodynamics that is based on the general equation for the nonequilibrium reversible-irreversible coupling (GENERIC) framework of nonequilibrium thermodynamics.

Smart Air-Water Interfaces with Arylazopyrazole Surfactants and Their Role in Photoresponsive Aqueous Foam.

A new light-switchable azo-surfactant arylazopyrazole tetraethylene glycol carboxylic acid (AAP-E) was used as a molecular building block to functionalize macroscopic foams. AAP-E was studied in the bulk solution with UV/vis spectroscopy and at the interface with sum-frequency generation (SFG) as well as tensiometry. Additional foaming experiments were performed with a dynamic foam analyzer to study the role of AAP-E surfactants at the ubiquitous air-water interface as well as within macroscopic foam.

Arylazopyrazole Photoswitches in Aqueous Solution: Substituent Effects, Photophysical Properties, and Host-Guest Chemistry.

Getting the green light! Substituted arylazopyrazoles (AAPs) have been investigated as supramolecular photoswitches in aqueous solution. Selective photostationary states (PSSs) and improved binding affinities to β-cyclodextrin have been determined. The experimental findings are supported by results from DFT calculations.

A Modular System for the Design of Stimuli-Responsive Multifunctional Nanoparticle Aggregates by Use of Host-Guest Chemistry.

A self-assembly approach for the design of multifunctional nanomaterials consisting of different nanoparticles (gold, iron oxide, and lanthanide-doped LiYF ) is developed. This modular system takes advantage of the light-responsive supramolecular host-guest chemistry of β-cyclodextrin and arylazopyrazole, which enables the dynamic and reversible self-assembly of particles to spherical nanoparticle aggregates in aqueous solution. Due to the magnetic iron oxide nanoparticles, the aggregates can be manipulated by an external magnetic field leading to the formation of linear structures.

Controlling Complex Stability in Photoresponsive Macromolecular Host-Guest Systems: Toward Reversible Capture of DNA by Cyclodextrin Vesicles.

An effective and universal method for delivering structurally diverse biomolecules in vivo would greatly benefit modern drug therapy, but has yet to be discovered. Self-assembled supramolecular complexes containing vesicles of amphiphilic cyclodextrin and linker molecules with an azobenzene guest unit and a charged functionality have been established as nanoscale carriers for proteins and DNA, making use of multivalent electrostatic attraction. However, light-induced cargo release is only feasible up to a maximum net charge of the biomacromolecules.

Self-assembly of colloidal molecules that respond to light and a magnetic field.

This communication reports a novel method to prepare Janus particles with light-responsive arylazopyrazole (AAP) polymer caps, which can be reversibly cross-linked to chain-like colloidal oligomers in the presence of cyclodextrin (CD) functionalized superparamagnetic nanoparticles. The resulting colloidal molecules are light-responsive and can be controlled by an external magnetic field.

Near-infrared photoswitching of cyclodextrin-guest complexes using lanthanide-doped LiYF upconversion nanoparticles.

This communication reports a new type of supramolecular cyclodextrin-guest complexes using cyclodextrin coated upconversion nanoparticles as hosts and monovalent and divalent azobenzenes and arylazopyrazoles as guests. A potentially biocompatible photocontrol of the interaction by isomerization of the azobenzene or arylazopyrazole was achieved by laser irradiation at 980 nm and a very low light intensity of 0.22 W cm.

Arylazopyrazoles as Light-Responsive Molecular Switches in Cyclodextrin-Based Supramolecular Systems.

A simple and high yield synthesis of water-soluble arylazopyrazoles (AAPs) featuring superior photophysical properties is reported. The introduction of a carboxylic acid allows the diverse functionalization of AAPs. Based on structural modifications of the switching unit the photophysical properties of the AAPs could be tuned to obtain molecular switches with favorable photostationary states.