Quantum monodromy in NCNCS - direct experimental confirmation.

Since the first confirmation of quantum monodromy in NCNCS (B. P. Winnewisser , Report No.

Improving Access to Tertiary Movement Disorders Subspecialty Care: A Team Model Born From the COVID-19 Crisis.

Patient demand continues to outpace growth of the neurology workforce, especially in its subspecialties such as movement disorders. Various strategies have been deployed to address this. The coronavirus disease 2019 pandemic accentuated the mismatch by propelling telemedicine and access demands to the forefront.

An option for improving access to outpatient general neurology.

Creating a team of nurse practitioner/physician assistant providers with a supervising physician is one potential model to extend limited physician resources for those medical specialties such as neurology, whose outpatient access is suboptimal. We offered new patient appointments with the access team. Monthly lead time (time to third available appointment) revealed that overall new-patient access improved from an average time-to-appointment wait of 299 days down to 10 days.

Pursuit of quantum monodromy in the far-infrared and mid-infrared spectra of NCNCS using synchrotron radiation.

Quantum monodromy has a dramatic and defining impact on all those physical properties of chain-molecules that depend on a large-amplitude bending coordinate, including in particular the distribution of the ro-vibrational energy levels. As revealed by its pure rotational (a-type) spectrum [B. P.

Laser induced amplified spontaneous emission from the f 0(g)(+) (3P0) ion-pair state of I2.

Laser induced amplified spontaneous emission (ASE) from the f 0g (+) ((3)P0) (vf = 1-7) ion-pair state of I2 was directly observed using an optical-optical double resonance technique with the B 0u (+) (vB = 21) valence state as the intermediate state. The emission detected at ~1660 nm was assigned to transitions from the f 0g (+) state to the D 0u (+) ((3)P2) ion-pair state. The transitions observed in the dispersed IR emission spectra were found to be between vibrational levels having the same vibrational quantum numbers in both electronic states, vf = vD.

Symbiotic bacteria induced necrotizing pancreatitis.

Context: Intestinal flora and anaerobes are frequently implicated in causing infectious necrotizing pancreatitis however Bifidobacterium and Veillonella have rarely been isolated as the causative agents. Bifidobacterium and Veillonella are commensal anaerobes which reside in gastrointestinal tract and help deconjugate bile acids. Bifidobacterium is also frequently used in probiotics.

Torsion-rotation coupling and the determination of the torsional potential energy function of HSOH.

Hindered torsional motion in a molecule such as HSOH leads to tunnelling splittings. Lying between the simpler limiting cases of strongly hindered torsion (the "we can simply neglect the tunnelling" limit) and that of free internal rotation (the "tunnelling pair of levels are just different vibrational states" limit) HSOH is particularly challenging due to strong and inherent torsion-rotation coupling. The low symmetry due to the different terminal moieties, SH and OH, further enriches the energy level pattern by allowing a systematic mixing within each quadruplet of torsion- and asymmetry-doubled levels.

Analysis of the FASSST rotational spectrum of NCNCS in view of quantum monodromy.

Quantum monodromy has a strong impact on the ro-vibrational energy levels of chain molecules whose bending potential energy function has the form of the bottom of a champagne bottle (i.e. with a hump or punt) around the linear configuration.

Moxifloxacin induced fatal hepatotoxicity in a 72-year-old man: a case report.

Moxifloxacin is a newer-generation synthetic fluoroquinolone that is used for treatment of acute bacterial sinusitis, acute exacerbation of chronic bronchitis, community acquired pneumonia, intra-abdominal infections and skin/skin structure infections. We describe a case of fatal hepatotoxicity caused by Moxifloxacin in a 72-year-old man. He presented with jaundice and epigastric tenderness that started one week after being treated for acute exacerbation of his chronic bronchitis with Moxifloxacin by his primary care physician.

Energy level promotion in the correlation from the tunnelling-doubled harmonic oscillator to the bi-rotor: application to internal rotation in molecules.

A surprisingly rich variety of phenomena are revealed in the energy level correlation between the limits of a tunnelling doubled harmonic oscillator and a bi-rotor. Some levels are found to have their vibrational quantum number "promoted" upon removal of the barrier to rotation, other levels, which we dub "invariant", are found to be completely independent of the barrier, while yet other levels exhibit a smooth transition between these limits. The general nature of these features can be understood in terms of the different degeneracies of the limiting cases.

Decay dynamics of the long-range H1Sigmag+ state of D2 and H2: experiment and theory.

We present accurate experimental measurements of the lifetimes of rovibrational levels of the long-range H1Sigmag+ state for both D2 and H2, obtained directly from the observation of the time-dependent decay of the fluorescence from these excited levels. These results improve upon and extend those of Reinhold et al. [J.

Experimental confirmation of quantum monodromy: the millimeter wave spectrum of cyanogen isothiocyanate NCNCS.

We have made energy-momentum maps for the experimental end-over-end rotational energy and the two-dimensional bending vibrational energy, both of which confirm the dominating effects of nontrivial quantum monodromy in cyanogen isothiocyanate. Accidental resonances in the rotational spectra yield accurate intervals between bending states.